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From the bottle: simple iron salts for the efficient synthesis of pyrrolidines via catalytic C–H bond amination
Commercially available iron salts FeX(2) are remarkably active catalysts for pyrrolidine formation from organic azides via direct C–H bond amination. With FeI(2), amination is fast and selective, (<30 min for 80% yield at 2 mol% loading), TONs up to 370 are reached with just 0.1 mol% catalyst, di...
| Autores principales: | , , |
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| Formato: | Online Artículo Texto |
| Lenguaje: | English |
| Publicado: |
The Royal Society of Chemistry
2023
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| Materias: | |
| Acceso en línea: | https://www.ncbi.nlm.nih.gov/pmc/articles/PMC9939938/ https://www.ncbi.nlm.nih.gov/pubmed/36825222 http://dx.doi.org/10.1039/d2cy02065c |