Inducing transient enantiomeric excess in a molecular quantum racemic mixture with microwave fields

Chiral molecules with low enantiomer interconversion barriers racemize even at cryogenic temperatures due to quantum tunneling, forming a racemic mixture that is impossible to separate using conventional chemical methods. Here we both experimentally and theoretically demonstrate a method to create a...

Descripción completa

Detalles Bibliográficos
Autores principales: Sun, Wenhao, Tikhonov, Denis S., Singh, Himanshi, Steber, Amanda L., Pérez, Cristóbal, Schnell, Melanie
Formato: Online Artículo Texto
Lenguaje:English
Publicado: Nature Publishing Group UK 2023
Materias:
Article
Acceso en línea:https://www.ncbi.nlm.nih.gov/pmc/articles/PMC9941128/
https://www.ncbi.nlm.nih.gov/pubmed/36807276
http://dx.doi.org/10.1038/s41467-023-36653-3

Internet

https://www.ncbi.nlm.nih.gov/pmc/articles/PMC9941128/
https://www.ncbi.nlm.nih.gov/pubmed/36807276
http://dx.doi.org/10.1038/s41467-023-36653-3

Ejemplares similares