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Inducing transient enantiomeric excess in a molecular quantum racemic mixture with microwave fields
Chiral molecules with low enantiomer interconversion barriers racemize even at cryogenic temperatures due to quantum tunneling, forming a racemic mixture that is impossible to separate using conventional chemical methods. Here we both experimentally and theoretically demonstrate a method to create a...
| Autores principales: | , , , , , |
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| Formato: | Online Artículo Texto |
| Lenguaje: | English |
| Publicado: |
Nature Publishing Group UK
2023
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| Materias: | |
| Acceso en línea: | https://www.ncbi.nlm.nih.gov/pmc/articles/PMC9941128/ https://www.ncbi.nlm.nih.gov/pubmed/36807276 http://dx.doi.org/10.1038/s41467-023-36653-3 |