Silylium-Catalyzed Regio- and Stereoselective Carbosilylation of Ynamides with Allylic Trimethylsilanes

[Image: see text] The regio- and stereoselective carbosilylation of tosylynamides with allylic trimethylsilanes takes place under mild conditions in the presence of catalytic TMSNTf(2) or HNTf(2) to give (Z)-α-allyl-β-trimethylsilylenamides with good yields. Theoretical calculations show the activat...

Descripción completa

Detalles Bibliográficos
Autores principales: Yepes, Paz, Suárez-Sobrino, Ángel L., Rodríguez, Miguel A., Ballesteros, Alfredo
Formato: Online Artículo Texto
Lenguaje:English
Publicado: American Chemical Society 2023
Acceso en línea:https://www.ncbi.nlm.nih.gov/pmc/articles/PMC9942199/
https://www.ncbi.nlm.nih.gov/pubmed/36749888
http://dx.doi.org/10.1021/acs.orglett.3c00221

Internet

https://www.ncbi.nlm.nih.gov/pmc/articles/PMC9942199/
https://www.ncbi.nlm.nih.gov/pubmed/36749888
http://dx.doi.org/10.1021/acs.orglett.3c00221

Ejemplares similares