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Silylium-Catalyzed Regio- and Stereoselective Carbosilylation of Ynamides with Allylic Trimethylsilanes

[Image: see text] The regio- and stereoselective carbosilylation of tosylynamides with allylic trimethylsilanes takes place under mild conditions in the presence of catalytic TMSNTf(2) or HNTf(2) to give (Z)-α-allyl-β-trimethylsilylenamides with good yields. Theoretical calculations show the activat...

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Detalles Bibliográficos
Autores principales:	Yepes, Paz, Suárez-Sobrino, Ángel L., Rodríguez, Miguel A., Ballesteros, Alfredo
Formato:	Online Artículo Texto
Lenguaje:	English
Publicado:	American Chemical Society 2023
Acceso en línea:	https://www.ncbi.nlm.nih.gov/pmc/articles/PMC9942199/ https://www.ncbi.nlm.nih.gov/pubmed/36749888 http://dx.doi.org/10.1021/acs.orglett.3c00221

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