Understanding and Expanding Zinc Cation/Amine Frustrated Lewis Pair Catalyzed C–H Borylation

[Image: see text] [(NacNac)Zn(DMT)][B(C(6)F(5))(4)], 1, (NacNac = {(2,6-(i)Pr(2)H(3)C(6))N(CH(3))C}(2)CH), DMT = N,N-dimethyl-4-toluidine), was synthesized via two routes starting from either (NacNac)ZnEt or (NacNac)ZnH. Complex 1 is an effective (pre)catalyst for the C–H borylation of (hetero)arene...

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Detalles Bibliográficos
Autores principales: Grundy, Matthew E., Sotorrios, Lia, Bisai, Milan Kumar, Yuan, Kang, Macgregor, Stuart A., Ingleson, Michael J.
Formato: Online Artículo Texto
Lenguaje:English
Publicado: American Chemical Society 2023
Acceso en línea:https://www.ncbi.nlm.nih.gov/pmc/articles/PMC9942201/
https://www.ncbi.nlm.nih.gov/pubmed/36846822
http://dx.doi.org/10.1021/acscatal.2c05995

Internet

https://www.ncbi.nlm.nih.gov/pmc/articles/PMC9942201/
https://www.ncbi.nlm.nih.gov/pubmed/36846822
http://dx.doi.org/10.1021/acscatal.2c05995

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