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Understanding and Expanding Zinc Cation/Amine Frustrated Lewis Pair Catalyzed C–H Borylation
[Image: see text] [(NacNac)Zn(DMT)][B(C(6)F(5))(4)], 1, (NacNac = {(2,6-(i)Pr(2)H(3)C(6))N(CH(3))C}(2)CH), DMT = N,N-dimethyl-4-toluidine), was synthesized via two routes starting from either (NacNac)ZnEt or (NacNac)ZnH. Complex 1 is an effective (pre)catalyst for the C–H borylation of (hetero)arene...
| Autores principales: | , , , , , |
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| Formato: | Online Artículo Texto |
| Lenguaje: | English |
| Publicado: |
American Chemical Society
2023
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| Acceso en línea: | https://www.ncbi.nlm.nih.gov/pmc/articles/PMC9942201/ https://www.ncbi.nlm.nih.gov/pubmed/36846822 http://dx.doi.org/10.1021/acscatal.2c05995 |