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Development of Immobilized Carreira (Phosphoramidite, Olefin) Ligands and Application in Iridium-Catalyzed Asymmetric Allylic Amination

[Image: see text] A family of polystyrene-supported (phosphoramidite, olefin) ligands L1–L4, based on the original design by Defieber and Carreira, has been developed and applied in iridium-catalyzed asymmetric allylic amination of unmasked allylic alcohols (27 examples, up to 99% ee). Among them, f...

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Detalles Bibliográficos
Autores principales: Zhou, Leijie, Zanda, Nicola, Chaudhari, Moreshwar, Da Silva, Mariane Felicio, Pericàs, Miquel A.
Formato: Online Artículo Texto
Lenguaje:English
Publicado: American Chemical Society 2023
Acceso en línea:https://www.ncbi.nlm.nih.gov/pmc/articles/PMC9942233/
https://www.ncbi.nlm.nih.gov/pubmed/36700541
http://dx.doi.org/10.1021/acs.joc.2c02589