Isolation of C1 through C4 derivatives from CO using heteroleptic uranium(iii) metallocene aryloxide complexes

The conversion of C1 feedstock molecules such as CO into commodity chemicals is a desirable, but challenging, endeavour. When the U(iii) complex, [(C(5)Me(5))(2)U(O-2,6-(t)Bu(2)-4-MeC(6)H(2))], is exposed to 1 atm of CO, only coordination is observed by IR spectroscopy as well as X-ray crystallograp...

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Detalles Bibliográficos
Autores principales: Ward, Robert J., del Rosal, Iker, Kelley, Steven P., Maron, Laurent, Walensky, Justin R.
Formato: Online Artículo Texto
Lenguaje:English
Publicado: The Royal Society of Chemistry 2023
Materias:
Chemistry
Acceso en línea:https://www.ncbi.nlm.nih.gov/pmc/articles/PMC9945253/
https://www.ncbi.nlm.nih.gov/pubmed/36845919
http://dx.doi.org/10.1039/d2sc06375a

Internet

https://www.ncbi.nlm.nih.gov/pmc/articles/PMC9945253/
https://www.ncbi.nlm.nih.gov/pubmed/36845919
http://dx.doi.org/10.1039/d2sc06375a

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