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From symmetry breaking to symmetry swapping: is Kasha's rule violated in multibranched phenyleneethynylenes?

The phenomenon of excited-state symmetry breaking is often observed in multipolar molecular systems, significantly affecting their photophysical and charge separation behavior. As a result of this phenomenon, the electronic excitation is partially localized in one of the molecular branches. However,...

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Detalles Bibliográficos
Autores principales: Swathi, K., Sujith, Meleppatt, Divya, P. S., P, Merin Varghese, Delledonne, Andrea, Phan Huu, D. K. Andrea, Di Maiolo, Francesco, Terenziani, Francesca, Lapini, Andrea, Painelli, Anna, Sissa, Cristina, Thomas, K. George
Formato: Online Artículo Texto
Lenguaje:English
Publicado: The Royal Society of Chemistry 2023
Materias:
Acceso en línea:https://www.ncbi.nlm.nih.gov/pmc/articles/PMC9945429/
https://www.ncbi.nlm.nih.gov/pubmed/36845926
http://dx.doi.org/10.1039/d2sc05206g