Catalytic Chemo-, Regio-, Diastereo-, and Enantioselective Bromochlorination of Unsaturated Systems Enabled by Lewis Base-Controlled Chloride Release

[Image: see text] A new strategy is described for the Lewis base-catalyzed bromochlorination of unsaturated systems that is mechanistically distinct from prior methodologies. The novelty of this method hinges on the utilization of thionyl chloride as a latent chloride source in combination with as l...

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Detalles Bibliográficos
Autores principales: Lubaev, Alexandra E., Rathnayake, Manjula D., Eze, Favour, Bayeh-Romero, Liela
Formato: Online Artículo Texto
Lenguaje:English
Publicado: American Chemical Society 2022
Acceso en línea:https://www.ncbi.nlm.nih.gov/pmc/articles/PMC9945878/
https://www.ncbi.nlm.nih.gov/pubmed/35820071
http://dx.doi.org/10.1021/jacs.2c04588

Internet

https://www.ncbi.nlm.nih.gov/pmc/articles/PMC9945878/
https://www.ncbi.nlm.nih.gov/pubmed/35820071
http://dx.doi.org/10.1021/jacs.2c04588

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