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Chromium-catalyzed stereodivergent E- and Z-selective alkyne hydrogenation controlled by cyclic (alkyl)(amino)carbene ligands

The hydrogenation of alkynes allows the synthesis of olefins, which are important feedstock for the materials, pharmaceutical, and petrochemical industry. Thus, methods that enable this transformation via low-cost metal catalysis are desirable. However, achieving stereochemical control in this react...

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Detalles Bibliográficos
Autores principales: Ling, Liang, Hu, Chenyang, Long, Linhong, Zhang, Xue, Zhao, Lixing, Liu, Liu Leo, Chen, Hui, Luo, Meiming, Zeng, Xiaoming
Formato: Online Artículo Texto
Lenguaje:English
Publicado: Nature Publishing Group UK 2023
Materias:
Acceso en línea:https://www.ncbi.nlm.nih.gov/pmc/articles/PMC9947122/
https://www.ncbi.nlm.nih.gov/pubmed/36813784
http://dx.doi.org/10.1038/s41467-023-36677-9