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σ-GeH and Germyl Cationic Pt(II) Complexes

[Image: see text] The low electron count Pt(II) complexes [Pt(NHC′)(NHC)][BAr(F)] (where NHC is a N-heterocyclic carbene ligand and NHC′ its metalated form) react with tertiary hydrogermanes HGeR(3) at room temperature to generate the 14-electron platinum(II) germyl derivatives [Pt(GeR(3))(NHC)(2)][...

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Detalles Bibliográficos
Autores principales: Laglera-Gándara, Carlos J., Ríos, Pablo, Fernández-de-Córdova, Francisco José, Barturen, Marina, Fernández, Israel, Conejero, Salvador
Formato: Online Artículo Texto
Lenguaje:English
Publicado: American Chemical Society 2022
Acceso en línea:https://www.ncbi.nlm.nih.gov/pmc/articles/PMC9949701/
https://www.ncbi.nlm.nih.gov/pubmed/36322561
http://dx.doi.org/10.1021/acs.inorgchem.2c03186