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σ-GeH and Germyl Cationic Pt(II) Complexes
[Image: see text] The low electron count Pt(II) complexes [Pt(NHC′)(NHC)][BAr(F)] (where NHC is a N-heterocyclic carbene ligand and NHC′ its metalated form) react with tertiary hydrogermanes HGeR(3) at room temperature to generate the 14-electron platinum(II) germyl derivatives [Pt(GeR(3))(NHC)(2)][...
Autores principales: | Laglera-Gándara, Carlos J., Ríos, Pablo, Fernández-de-Córdova, Francisco José, Barturen, Marina, Fernández, Israel, Conejero, Salvador |
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Formato: | Online Artículo Texto |
Lenguaje: | English |
Publicado: |
American Chemical Society
2022
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Acceso en línea: | https://www.ncbi.nlm.nih.gov/pmc/articles/PMC9949701/ https://www.ncbi.nlm.nih.gov/pubmed/36322561 http://dx.doi.org/10.1021/acs.inorgchem.2c03186 |
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