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Metal Node Control of Brønsted Acidity in Heterobimetallic Titanium–Organic Frameworks

[Image: see text] Compared to indirect framework modification, synthetic control of cluster composition can be used to gain direct access to catalytic activities exclusive of specific metal combinations. We demonstrate this concept by testing the aminolysis of epoxides with a family of isostructural...

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Detalles Bibliográficos
Autores principales: Rubio-Gaspar, Ana, Navalón, Sergio, Tatay, Sergio, Cirujano, Francisco G., Fernández-Conde, Carmen, Padial, Natalia M., Martí-Gastaldo, Carlos
Formato: Online Artículo Texto
Lenguaje:English
Publicado: American Chemical Society 2023
Acceso en línea:https://www.ncbi.nlm.nih.gov/pmc/articles/PMC9951219/
https://www.ncbi.nlm.nih.gov/pubmed/36689481
http://dx.doi.org/10.1021/jacs.2c12718