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Catalytic Asymmetric Michael Reaction of Methyl Alkynyl Ketone Catalyzed by Diphenylprolinol Silyl Ether

[Image: see text] The asymmetric Michael reaction of methyl alkynyl ketone and α,β-unsaturated aldehyde catalyzed by diphenylprolinol silyl ether was developed. Although methyl alkynyl ketone is a good Michael acceptor, it also acts as a Michael donor to afford the synthetically important δ-oxo alde...

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Detalles Bibliográficos
Autores principales: Umekubo, Nariyoshi, Hayashi, Yujiro
Formato: Online Artículo Texto
Lenguaje:English
Publicado: American Chemical Society 2022
Acceso en línea:https://www.ncbi.nlm.nih.gov/pmc/articles/PMC9954212/
https://www.ncbi.nlm.nih.gov/pubmed/36855469
http://dx.doi.org/10.1021/acsorginorgau.1c00054