Enabling Cyclization Strategies through Carbonyl-Ylide-Mediated Synthesis of Malonate Enol Ethers

[Image: see text] Malonate enol ethers are afforded in one step by condensation of cyclic ketones with α-diazomalonates under [CpRu(CH(3)CN)(3)][BAr(F)] catalysis. The dual reactivity of these 2-vinyloxymalonates can be used to expand the classical range of cyclizations derived from carbonyl ylide i...

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Detalles Bibliográficos
Autores principales: Viñas-Lóbez, Júlia, Levitre, Guillaume, de Aguirre, Adiran, Besnard, Céline, Poblador-Bahamonde, Amalia I., Lacour, Jérôme
Formato: Online Artículo Texto
Lenguaje:English
Publicado: American Chemical Society 2021
Acceso en línea:https://www.ncbi.nlm.nih.gov/pmc/articles/PMC9954264/
https://www.ncbi.nlm.nih.gov/pubmed/36855638
http://dx.doi.org/10.1021/acsorginorgau.1c00006

Internet

https://www.ncbi.nlm.nih.gov/pmc/articles/PMC9954264/
https://www.ncbi.nlm.nih.gov/pubmed/36855638
http://dx.doi.org/10.1021/acsorginorgau.1c00006

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