Enabling Cyclization Strategies through Carbonyl-Ylide-Mediated Synthesis of Malonate Enol Ethers

[Image: see text] Malonate enol ethers are afforded in one step by condensation of cyclic ketones with α-diazomalonates under [CpRu(CH(3)CN)(3)][BAr(F)] catalysis. The dual reactivity of these 2-vinyloxymalonates can be used to expand the classical range of cyclizations derived from carbonyl ylide i...

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Autores principales: Viñas-Lóbez, Júlia, Levitre, Guillaume, de Aguirre, Adiran, Besnard, Céline, Poblador-Bahamonde, Amalia I., Lacour, Jérôme
Formato: Online Artículo Texto
Lenguaje:English
Publicado: American Chemical Society 2021
Acceso en línea:https://www.ncbi.nlm.nih.gov/pmc/articles/PMC9954264/
https://www.ncbi.nlm.nih.gov/pubmed/36855638
http://dx.doi.org/10.1021/acsorginorgau.1c00006
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author Viñas-Lóbez, Júlia
Levitre, Guillaume
de Aguirre, Adiran
Besnard, Céline
Poblador-Bahamonde, Amalia I.
Lacour, Jérôme
author_facet Viñas-Lóbez, Júlia
Levitre, Guillaume
de Aguirre, Adiran
Besnard, Céline
Poblador-Bahamonde, Amalia I.
Lacour, Jérôme
author_sort Viñas-Lóbez, Júlia
collection PubMed
description [Image: see text] Malonate enol ethers are afforded in one step by condensation of cyclic ketones with α-diazomalonates under [CpRu(CH(3)CN)(3)][BAr(F)] catalysis. The dual reactivity of these 2-vinyloxymalonates can be used to expand the classical range of cyclizations derived from carbonyl ylide intermediates.
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spelling pubmed-99542642023-02-27 Enabling Cyclization Strategies through Carbonyl-Ylide-Mediated Synthesis of Malonate Enol Ethers Viñas-Lóbez, Júlia Levitre, Guillaume de Aguirre, Adiran Besnard, Céline Poblador-Bahamonde, Amalia I. Lacour, Jérôme ACS Org Inorg Au [Image: see text] Malonate enol ethers are afforded in one step by condensation of cyclic ketones with α-diazomalonates under [CpRu(CH(3)CN)(3)][BAr(F)] catalysis. The dual reactivity of these 2-vinyloxymalonates can be used to expand the classical range of cyclizations derived from carbonyl ylide intermediates. American Chemical Society 2021-05-05 /pmc/articles/PMC9954264/ /pubmed/36855638 http://dx.doi.org/10.1021/acsorginorgau.1c00006 Text en © 2021 The Authors. Published by American Chemical Society https://creativecommons.org/licenses/by-nc-nd/4.0/Permits non-commercial access and re-use, provided that author attribution and integrity are maintained; but does not permit creation of adaptations or other derivative works (https://creativecommons.org/licenses/by-nc-nd/4.0/).
spellingShingle Viñas-Lóbez, Júlia
Levitre, Guillaume
de Aguirre, Adiran
Besnard, Céline
Poblador-Bahamonde, Amalia I.
Lacour, Jérôme
Enabling Cyclization Strategies through Carbonyl-Ylide-Mediated Synthesis of Malonate Enol Ethers
title Enabling Cyclization Strategies through Carbonyl-Ylide-Mediated Synthesis of Malonate Enol Ethers
title_full Enabling Cyclization Strategies through Carbonyl-Ylide-Mediated Synthesis of Malonate Enol Ethers
title_fullStr Enabling Cyclization Strategies through Carbonyl-Ylide-Mediated Synthesis of Malonate Enol Ethers
title_full_unstemmed Enabling Cyclization Strategies through Carbonyl-Ylide-Mediated Synthesis of Malonate Enol Ethers
title_short Enabling Cyclization Strategies through Carbonyl-Ylide-Mediated Synthesis of Malonate Enol Ethers
title_sort enabling cyclization strategies through carbonyl-ylide-mediated synthesis of malonate enol ethers
url https://www.ncbi.nlm.nih.gov/pmc/articles/PMC9954264/
https://www.ncbi.nlm.nih.gov/pubmed/36855638
http://dx.doi.org/10.1021/acsorginorgau.1c00006
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