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Straightforward Synthesis of Indenes by Gold-Catalyzed Intramolecular Hydroalkylation of Ynamides

[Image: see text] An original and straightforward entry to polysubstituted indenes from readily available ynamides is reported. Upon reaction with a N-heterocyclic carbene–gold complex under mild conditions, activated keteniminium ions are generated whose unique electrophilicity triggers a [1,5]-hyd...

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Detalles Bibliográficos
Autores principales: Thilmany, Pierre, Guarnieri-Ibáñez, Alejandro, Jacob, Clément, Lacour, Jérôme, Evano, Gwilherm
Formato: Online Artículo Texto
Lenguaje:English
Publicado: American Chemical Society 2021
Acceso en línea:https://www.ncbi.nlm.nih.gov/pmc/articles/PMC9954284/
https://www.ncbi.nlm.nih.gov/pubmed/36855401
http://dx.doi.org/10.1021/acsorginorgau.1c00021