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Cu(I)-azidopyrrolo[3,2-d]pyrimidine Catalyzed Glaser–Hay Reaction under Mild Conditions

[Image: see text] The limitation of the CuAAC “click” reaction with a 2-azidopyridine substrate, owing to its equilibrium with a tetrazole isomer, is exploited herein for its utility in the Glaser–Hay reaction. A catalytic combination of a 2-azidopyridine analogue, 4-azido-5H-pyrrolo[3,2-d]pyrimidin...

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Detalles Bibliográficos
Autores principales: Thangarasu, Arun K., Yadhukrishnan, Velickakathu O., Krishnakumar, K. A., Varma, Sanjay Suresh, Lankalapalli, Ravi S.
Formato: Online Artículo Texto
Lenguaje:English
Publicado: American Chemical Society 2021
Acceso en línea:https://www.ncbi.nlm.nih.gov/pmc/articles/PMC9954286/
https://www.ncbi.nlm.nih.gov/pubmed/36855403
http://dx.doi.org/10.1021/acsorginorgau.1c00015