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Effect of Borate Cocatalysts toward Activity and Comonomer Incorporation in Ethylene Copolymerization by Half-Titanocene Catalysts in Methylcyclohexane

[Image: see text] Ethylene copolymerizations with 2-methyl-1-pentene, 1-dodecene (DD), vinylcyclohexane (VCH), [Me(2)Si(C(5)Me(4))(N(t)Bu)]TiCl(2) (1), Cp*TiMe(2)(O-2,6-(i)Pr(2)-4-RC(6)H(2)) [R = H (2), SiEt(3) (3)]–borate, and [A(H)](+)[BAr(4)](−) [Ar = C(6)F(5); A(H)(+) = N(+)(H)Me(n-C(18)H(37))(2...

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Detalles Bibliográficos
Autores principales: Kitphaitun, Suphitchaya, Fujimoto, Takuya, Ochi, Yosuke, Nomura, Kotohiro
Formato: Online Artículo Texto
Lenguaje:English
Publicado: American Chemical Society 2022
Acceso en línea:https://www.ncbi.nlm.nih.gov/pmc/articles/PMC9955119/
https://www.ncbi.nlm.nih.gov/pubmed/36855669
http://dx.doi.org/10.1021/acsorginorgau.2c00020