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Effect of Borate Cocatalysts toward Activity and Comonomer Incorporation in Ethylene Copolymerization by Half-Titanocene Catalysts in Methylcyclohexane
[Image: see text] Ethylene copolymerizations with 2-methyl-1-pentene, 1-dodecene (DD), vinylcyclohexane (VCH), [Me(2)Si(C(5)Me(4))(N(t)Bu)]TiCl(2) (1), Cp*TiMe(2)(O-2,6-(i)Pr(2)-4-RC(6)H(2)) [R = H (2), SiEt(3) (3)]–borate, and [A(H)](+)[BAr(4)](−) [Ar = C(6)F(5); A(H)(+) = N(+)(H)Me(n-C(18)H(37))(2...
Autores principales: | Kitphaitun, Suphitchaya, Fujimoto, Takuya, Ochi, Yosuke, Nomura, Kotohiro |
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Formato: | Online Artículo Texto |
Lenguaje: | English |
Publicado: |
American Chemical Society
2022
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Acceso en línea: | https://www.ncbi.nlm.nih.gov/pmc/articles/PMC9955119/ https://www.ncbi.nlm.nih.gov/pubmed/36855669 http://dx.doi.org/10.1021/acsorginorgau.2c00020 |
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