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Substituent-Induced Control of fac/mer Isomerism in Azine-NHC Fe(II) Complexes

[Image: see text] The stereoselective synthesis of geometrical iron(II) complexes bearing azine-NHC ligands is described. Facial and meridional selectivity is achieved as a function of the steric demand of the azine unit, with no remarkable influence of the carbene nature. More specifically, meridio...

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Detalles Bibliográficos
Autores principales: Carrillo, Ulises, Francés-Monerris, Antonio, Marri, Anil Reddy, Cebrián, Cristina, Gros, Philippe C.
Formato: Online Artículo Texto
Lenguaje:English
Publicado: American Chemical Society 2022
Acceso en línea:https://www.ncbi.nlm.nih.gov/pmc/articles/PMC9955161/
https://www.ncbi.nlm.nih.gov/pubmed/36855530
http://dx.doi.org/10.1021/acsorginorgau.2c00038