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Substituent-Induced Control of fac/mer Isomerism in Azine-NHC Fe(II) Complexes
[Image: see text] The stereoselective synthesis of geometrical iron(II) complexes bearing azine-NHC ligands is described. Facial and meridional selectivity is achieved as a function of the steric demand of the azine unit, with no remarkable influence of the carbene nature. More specifically, meridio...
Autores principales: | , , , , |
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Formato: | Online Artículo Texto |
Lenguaje: | English |
Publicado: |
American Chemical Society
2022
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Acceso en línea: | https://www.ncbi.nlm.nih.gov/pmc/articles/PMC9955161/ https://www.ncbi.nlm.nih.gov/pubmed/36855530 http://dx.doi.org/10.1021/acsorginorgau.2c00038 |