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Alternatives to Iridium: A Polyaza[7]helicene as a Strongly Reductive Visible Light Photoredox Catalyst

[Image: see text] The use of a readily accessible polyazahelicene as a strongly reducing metal-free alternative to the commonly used precious metal based photoredox catalysts is demonstrated. An improved two-step synthesis of the catalyst is described, and its photophysical properties with respect t...

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Detalles Bibliográficos
Autores principales: Rocker, Johannes, Opatz, Till
Formato: Online Artículo Texto
Lenguaje:English
Publicado: American Chemical Society 2022
Acceso en línea:https://www.ncbi.nlm.nih.gov/pmc/articles/PMC9955290/
https://www.ncbi.nlm.nih.gov/pubmed/36855668
http://dx.doi.org/10.1021/acsorginorgau.2c00022