Theoretical Study on the Origin of Abnormal Regioselectivity in Ring-Opening Reaction of Hexafluoropropylene Oxide

That nucleophiles preferentially attack at the less sterically hindered carbon of epoxides under neutral and basic conditions has been generally accepted as a fundamental rule for predicting the regioselectivity of this type of reaction. However, this rule does not hold for perfluorinated epoxides,...

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Detalles Bibliográficos
Autores principales: Yu, Cui, Sang, Yueqian, Li, Yao, Xue, Xiaosong
Formato: Online Artículo Texto
Lenguaje:English
Publicado: MDPI 2023
Materias:
Communication
Acceso en línea:https://www.ncbi.nlm.nih.gov/pmc/articles/PMC9962681/
https://www.ncbi.nlm.nih.gov/pubmed/36838653
http://dx.doi.org/10.3390/molecules28041669

Internet

https://www.ncbi.nlm.nih.gov/pmc/articles/PMC9962681/
https://www.ncbi.nlm.nih.gov/pubmed/36838653
http://dx.doi.org/10.3390/molecules28041669

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