Unprecedented Elimination Reactions of Cyclic Aldols: A New Biosynthetic Pathway toward the Taiwaniaquinoid Skeleton

The acid treatment of 6,7-seco-abietane dialdehydes gives, in high yield, the corresponding derivatives with the 4a-methyltetrahydrofluorene skeleton of taiwaniaquinoids. A mechanism involving the elimination of formic acid from the cyclic aldol intermediate is proposed here. This process can be pos...

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Detalles Bibliográficos
Autores principales: Guardia, Juan J., Fernández, Antonio, Justicia, José, Zentar, Houda, Alvarez-Manzaneda, Ramón, Alvarez-Manzaneda, Enrique, Chahboun, Rachid
Formato: Online Artículo Texto
Lenguaje:English
Publicado: MDPI 2023
Materias:
Article
Acceso en línea:https://www.ncbi.nlm.nih.gov/pmc/articles/PMC9965844/
https://www.ncbi.nlm.nih.gov/pubmed/36838511
http://dx.doi.org/10.3390/molecules28041524

Internet

https://www.ncbi.nlm.nih.gov/pmc/articles/PMC9965844/
https://www.ncbi.nlm.nih.gov/pubmed/36838511
http://dx.doi.org/10.3390/molecules28041524

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