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Enantioseparation of P-Stereogenic 1-Adamantyl Arylthiophosphonates and Their Stereospecific Transformation to 1-Adamantyl Aryl-H-phosphinates

A focused library of 1-adamantyl arylthiophosphonates was prepared in racemic form. An enantioseparation method was developed for P-stereogenic thiophosphonates using (S)-1-phenylethylamine as the resolving agent. Under optimized conditions, three out of the five arylthiophosphonates were prepared i...

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Detalles Bibliográficos
Autores principales: Varga, Bence, Buna, Levente, Vincze, Daniella, Holczbauer, Tamás, Mátravölgyi, Béla, Fogassy, Elemér, Keglevich, György, Bagi, Péter
Formato: Online Artículo Texto
Lenguaje:English
Publicado: MDPI 2023
Materias:
Acceso en línea:https://www.ncbi.nlm.nih.gov/pmc/articles/PMC9966292/
https://www.ncbi.nlm.nih.gov/pubmed/36838571
http://dx.doi.org/10.3390/molecules28041584