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Cobalt(III)-catalyzed asymmetric ring-opening of 7-oxabenzonorbornadienes via indole C–H functionalization

Asymmetric ring-opening of 7-oxabenzonorbornadienes is achieved via Co-catalyzed indole C–H functionalization. The utilization of chiral Co-catalyst consisting of a binaphthyl-derived trisubstituted cyclopentadienyl ligand resulted in high yields (up to 99%) and excellent enantioselectivity (>99%...

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Detalles Bibliográficos
Autores principales: Zheng, Yang, Zhang, Wen-Yun, Gu, Qing, Zheng, Chao, You, Shu-Li
Formato: Online Artículo Texto
Lenguaje:English
Publicado: Nature Publishing Group UK 2023
Materias:
Acceso en línea:https://www.ncbi.nlm.nih.gov/pmc/articles/PMC9968317/
https://www.ncbi.nlm.nih.gov/pubmed/36841798
http://dx.doi.org/10.1038/s41467-023-36723-6