Reactions of an Osmium–Hexahydride Complex with 2-Butyne and 3-Hexyne and Their Performance in the Migratory Hydroboration of Aliphatic Internal Alkynes

[Image: see text] Reactions of the hexahydride OsH(6)(P(i)Pr(3))(2) (1) with 2-butyne and 3-hexyne and the behavior of the resulting species toward pinacolborane (pinBH) have been investigated in the search for new hydroboration processes. Complex 1 reacts with 2-butyne to give 1-butene and the osma...

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Detalles Bibliográficos
Autores principales: Babón, Juan C., Esteruelas, Miguel A., López, Ana M., Oñate, Enrique
Formato: Online Artículo Texto
Lenguaje:English
Publicado: American Chemical Society 2022
Acceso en línea:https://www.ncbi.nlm.nih.gov/pmc/articles/PMC9969483/
https://www.ncbi.nlm.nih.gov/pubmed/36864948
http://dx.doi.org/10.1021/acs.organomet.2c00338

Internet

https://www.ncbi.nlm.nih.gov/pmc/articles/PMC9969483/
https://www.ncbi.nlm.nih.gov/pubmed/36864948
http://dx.doi.org/10.1021/acs.organomet.2c00338

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