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Reactions of an Osmium–Hexahydride Complex with 2-Butyne and 3-Hexyne and Their Performance in the Migratory Hydroboration of Aliphatic Internal Alkynes
[Image: see text] Reactions of the hexahydride OsH(6)(P(i)Pr(3))(2) (1) with 2-butyne and 3-hexyne and the behavior of the resulting species toward pinacolborane (pinBH) have been investigated in the search for new hydroboration processes. Complex 1 reacts with 2-butyne to give 1-butene and the osma...
| Autores principales: | , , , |
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| Formato: | Online Artículo Texto |
| Lenguaje: | English |
| Publicado: |
American Chemical Society
2022
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| Acceso en línea: | https://www.ncbi.nlm.nih.gov/pmc/articles/PMC9969483/ https://www.ncbi.nlm.nih.gov/pubmed/36864948 http://dx.doi.org/10.1021/acs.organomet.2c00338 |