Silyl-Osmium(IV)-Trihydride Complexes Stabilized by a Pincer Ether-Diphosphine: Formation and Reactions with Alkynes

[Image: see text] Complex OsH(4){κ(3)-P,O,P-[xant(P(i)Pr(2))(2)]} (1) activates the Si–H bond of triethylsilane, triphenylsilane, and 1,1,1,3,5,5,5-heptamethyltrisiloxane to give the silyl-osmium(IV)-trihydride derivatives OsH(3)(SiR(3)){κ(3)-P,O,P-[xant(P(i)Pr(2))(2)]} [SiR(3) = SiEt(3) (2), SiPh(3...

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Detalles Bibliográficos
Autores principales: Babón, Juan C., Esteruelas, Miguel A., Oñate, Enrique, Paz, Sonia, Vélez, Andrea
Formato: Online Artículo Texto
Lenguaje:English
Publicado: American Chemical Society 2022
Acceso en línea:https://www.ncbi.nlm.nih.gov/pmc/articles/PMC9969874/
https://www.ncbi.nlm.nih.gov/pubmed/36866234
http://dx.doi.org/10.1021/acs.organomet.2c00201

Internet

https://www.ncbi.nlm.nih.gov/pmc/articles/PMC9969874/
https://www.ncbi.nlm.nih.gov/pubmed/36866234
http://dx.doi.org/10.1021/acs.organomet.2c00201

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