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Silyl-Osmium(IV)-Trihydride Complexes Stabilized by a Pincer Ether-Diphosphine: Formation and Reactions with Alkynes
[Image: see text] Complex OsH(4){κ(3)-P,O,P-[xant(P(i)Pr(2))(2)]} (1) activates the Si–H bond of triethylsilane, triphenylsilane, and 1,1,1,3,5,5,5-heptamethyltrisiloxane to give the silyl-osmium(IV)-trihydride derivatives OsH(3)(SiR(3)){κ(3)-P,O,P-[xant(P(i)Pr(2))(2)]} [SiR(3) = SiEt(3) (2), SiPh(3...
| Autores principales: | , , , , |
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| Formato: | Online Artículo Texto |
| Lenguaje: | English |
| Publicado: |
American Chemical Society
2022
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| Acceso en línea: | https://www.ncbi.nlm.nih.gov/pmc/articles/PMC9969874/ https://www.ncbi.nlm.nih.gov/pubmed/36866234 http://dx.doi.org/10.1021/acs.organomet.2c00201 |