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Electrochemical Cycloaddition Reactions of Alkene Radical Cations: A Route toward Cyclopropanes and Cyclobutanes

[Image: see text] Herein, we describe a mild and efficient electrochemical method for cycloaddition reactions of alkene radical cations. Anodic oxidation of olefins produces electrophilic alkene radical cations, which further react with either diazo compounds in a [2 + 1] cycloaddition toward cyclop...

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Detalles Bibliográficos
Autores principales: Rybicka-Jasińska, Katarzyna, Szeptuch, Zuzanna, Kubiszewski, Hubert, Kowaluk, Agnieszka
Formato: Online Artículo Texto
Lenguaje:English
Publicado: American Chemical Society 2023
Acceso en línea:https://www.ncbi.nlm.nih.gov/pmc/articles/PMC9972478/
https://www.ncbi.nlm.nih.gov/pubmed/36786497
http://dx.doi.org/10.1021/acs.orglett.3c00121