Rh(I) Complexes with Hemilabile Thioether-Functionalized NHC Ligands as Catalysts for [2 + 2 + 2] Cycloaddition of 1,5-Bisallenes and Alkynes

[Image: see text] The [2 + 2 + 2] cycloaddition of 1,5-bisallenes and alkynes under the catalysis of Rh(I) with hemilabile thioether-functionalized N-heterocyclic carbene ligands is described. This protocol effectively provides an entry to different trans-5,6-fused bicyclic systems with two exocycli...

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Detalles Bibliográficos
Autores principales: Vila, Jordi, Solà, Miquel, Achard, Thierry, Bellemin-Laponnaz, Stéphane, Pla-Quintana, Anna, Roglans, Anna
Formato: Online Artículo Texto
Lenguaje:English
Publicado: American Chemical Society 2023
Acceso en línea:https://www.ncbi.nlm.nih.gov/pmc/articles/PMC9990073/
https://www.ncbi.nlm.nih.gov/pubmed/36910871
http://dx.doi.org/10.1021/acscatal.2c05790

Internet

https://www.ncbi.nlm.nih.gov/pmc/articles/PMC9990073/
https://www.ncbi.nlm.nih.gov/pubmed/36910871
http://dx.doi.org/10.1021/acscatal.2c05790

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