Carbonyl­bis­{6,6′-[(3,3′-di-tert-butyl-5,5′-dimeth­oxy-1,1′-biphenyl-2,2′-di­yl)bis(oxy)]bis­(dibenzo[d,f][1,3,2]-dioxaphosphepine)}hydridorhodium(I) toluene-d (8) 2.25-solvate

The crystal-structure determination of the title compound, [RhH(C(46)H(44)O(8)P(2))(2)(CO)]·2.25C(7)D(8), is reported. The bis­phosphite ligand, C(46)H(44)O(8)P(2), is well known as Biphephos. One specific characteristic of this hydrido rhodium(I) monocarbonyl complex is that one bis­phosphite ligan...

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Detalles Bibliográficos
Autores principales: Leidecker, Benedict N., Spannenberg, Anke, Franke, Robert, Börner, Armin, Kubis, Christoph
Formato: Online Artículo Texto
Lenguaje:English
Publicado: International Union of Crystallography 2023
Materias:
Data Reports
Acceso en línea:https://www.ncbi.nlm.nih.gov/pmc/articles/PMC9993892/
https://www.ncbi.nlm.nih.gov/pubmed/36911081
http://dx.doi.org/10.1107/S2414314623000834

Internet

https://www.ncbi.nlm.nih.gov/pmc/articles/PMC9993892/
https://www.ncbi.nlm.nih.gov/pubmed/36911081
http://dx.doi.org/10.1107/S2414314623000834

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