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Carbonylbis{6,6′-[(3,3′-di-tert-butyl-5,5′-dimethoxy-1,1′-biphenyl-2,2′-diyl)bis(oxy)]bis(dibenzo[d,f][1,3,2]-dioxaphosphepine)}hydridorhodium(I) toluene-d (8) 2.25-solvate

The crystal-structure determination of the title compound, [RhH(C(46)H(44)O(8)P(2))(2)(CO)]·2.25C(7)D(8), is reported. The bisphosphite ligand, C(46)H(44)O(8)P(2), is well known as Biphephos. One specific characteristic of this hydrido rhodium(I) monocarbonyl complex is that one bisphosphite ligan...

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Detalles Bibliográficos
Autores principales:	Leidecker, Benedict N., Spannenberg, Anke, Franke, Robert, Börner, Armin, Kubis, Christoph
Formato:	Online Artículo Texto
Lenguaje:	English
Publicado:	International Union of Crystallography 2023
Materias:	Data Reports
Acceso en línea:	https://www.ncbi.nlm.nih.gov/pmc/articles/PMC9993892/ https://www.ncbi.nlm.nih.gov/pubmed/36911081 http://dx.doi.org/10.1107/S2414314623000834

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