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(η(5)-Carb­oxy­cyclo­penta­dien­yl)(η(7)-cyclo­hepta­trien­yl)manganese(I) hexa­fluorido­phosphate

The title compound, [Mn(C(7)H(7))(C(6)H(5)O(2))]PF(6) or [(Cht)Mn(Cp’CO(2)H)]PF(6), with Cht = cyclo­hepta­trienyl and Cp’ = C(5)H(4), is an air-stable, purple, heteroleptic, cationic sandwich complex with manganese in oxidation state +I and π-coordinating cyclo­hepta­trienyl and cyclo­penta­dienyl...

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Detalles Bibliográficos
Autores principales: Thaler, Reinhard, Wurst, Klaus, Bildstein, Benno
Formato: Online Artículo Texto
Lenguaje:English
Publicado: International Union of Crystallography 2023
Materias:
Acceso en línea:https://www.ncbi.nlm.nih.gov/pmc/articles/PMC9993894/
https://www.ncbi.nlm.nih.gov/pubmed/36911078
http://dx.doi.org/10.1107/S2414314623001074