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(η(5)-Carboxycyclopentadienyl)(η(7)-cycloheptatrienyl)manganese(I) hexafluoridophosphate
The title compound, [Mn(C(7)H(7))(C(6)H(5)O(2))]PF(6) or [(Cht)Mn(Cp’CO(2)H)]PF(6), with Cht = cycloheptatrienyl and Cp’ = C(5)H(4), is an air-stable, purple, heteroleptic, cationic sandwich complex with manganese in oxidation state +I and π-coordinating cycloheptatrienyl and cyclopentadienyl...
Autores principales: | Thaler, Reinhard, Wurst, Klaus, Bildstein, Benno |
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Formato: | Online Artículo Texto |
Lenguaje: | English |
Publicado: |
International Union of Crystallography
2023
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Materias: | |
Acceso en línea: | https://www.ncbi.nlm.nih.gov/pmc/articles/PMC9993894/ https://www.ncbi.nlm.nih.gov/pubmed/36911078 http://dx.doi.org/10.1107/S2414314623001074 |
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