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Post-Cyclization Skeletal Rearrangements in Plant Triterpenoid Biosynthesis by a Pair of Branchpoint Isomerases

[Image: see text] Triterpenoids possess potent biological activities, but their polycyclic skeletons are challenging to synthesize. The skeletal diversity of triterpenoids in plants is generated by oxidosqualene cyclases based on epoxide-triggered cationic rearrangement cascades. Normally, triterpen...

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Detalles Bibliográficos
Autores principales: Chuang, Ling, Liu, Shenyu, Franke, Jakob
Formato: Online Artículo Texto
Lenguaje:English
Publicado: American Chemical Society 2023
Acceso en línea:https://www.ncbi.nlm.nih.gov/pmc/articles/PMC9999417/
https://www.ncbi.nlm.nih.gov/pubmed/36821810
http://dx.doi.org/10.1021/jacs.2c10838