[2,6-Bis(5-chloropyrimidin-2-yl-κN)pyridine-κN](2,2′:6′,2′′-terpyridine-κ(3) N,N′,N′′)ruthenium(II) bis(hexafluoridophosphate) acetonitrile disolvate
In the title compound, [Ru(C(13)H(7)Cl(2)N(5))(C(15)H(11)N(3))](PF(6))(2)·2CH(3)CN, the Ru(II) atom is coordinated in a distorted octahedral geometry by a tridentate 2,2′:6′,2′′-terpyridine ligand and a tridentate 2,6-bis(5-chloropyrimidin-2-yl)pyridine ligand. Least-squares mean-plane distortion...
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Formato: | Texto |
Lenguaje: | English |
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International Union of Crystallography
2008
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Materias: | |
Acceso en línea: | https://www.ncbi.nlm.nih.gov/pmc/articles/PMC2960288/ https://www.ncbi.nlm.nih.gov/pubmed/21201294 http://dx.doi.org/10.1107/S1600536807068602 |
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author | Medlycott, Elaine A. Wang, Jianhua Hanan, Garry S. |
author_facet | Medlycott, Elaine A. Wang, Jianhua Hanan, Garry S. |
author_sort | Medlycott, Elaine A. |
collection | PubMed |
description | In the title compound, [Ru(C(13)H(7)Cl(2)N(5))(C(15)H(11)N(3))](PF(6))(2)·2CH(3)CN, the Ru(II) atom is coordinated in a distorted octahedral geometry by a tridentate 2,2′:6′,2′′-terpyridine ligand and a tridentate 2,6-bis(5-chloropyrimidin-2-yl)pyridine ligand. Least-squares mean-plane distortions of only 1.72 (2) and 2.91 (2)° of the pyrimidyl rings with respect to the central pyridine are observed for the bis(pyrimidyl)pyridine-based tridentate ligand, while the distal pyridyl rings of terpyridine twist by 13.43 (7) and 4.68 (9)° away from the central pyridine ring. |
format | Text |
id | pubmed-2960288 |
institution | National Center for Biotechnology Information |
language | English |
publishDate | 2008 |
publisher | International Union of Crystallography |
record_format | MEDLINE/PubMed |
spelling | pubmed-29602882010-12-30 [2,6-Bis(5-chloropyrimidin-2-yl-κN)pyridine-κN](2,2′:6′,2′′-terpyridine-κ(3) N,N′,N′′)ruthenium(II) bis(hexafluoridophosphate) acetonitrile disolvate Medlycott, Elaine A. Wang, Jianhua Hanan, Garry S. Acta Crystallogr Sect E Struct Rep Online Metal-Organic Papers In the title compound, [Ru(C(13)H(7)Cl(2)N(5))(C(15)H(11)N(3))](PF(6))(2)·2CH(3)CN, the Ru(II) atom is coordinated in a distorted octahedral geometry by a tridentate 2,2′:6′,2′′-terpyridine ligand and a tridentate 2,6-bis(5-chloropyrimidin-2-yl)pyridine ligand. Least-squares mean-plane distortions of only 1.72 (2) and 2.91 (2)° of the pyrimidyl rings with respect to the central pyridine are observed for the bis(pyrimidyl)pyridine-based tridentate ligand, while the distal pyridyl rings of terpyridine twist by 13.43 (7) and 4.68 (9)° away from the central pyridine ring. International Union of Crystallography 2008-01-09 /pmc/articles/PMC2960288/ /pubmed/21201294 http://dx.doi.org/10.1107/S1600536807068602 Text en © International Union of Crystallography 2008 http://journals.iucr.org/services/termsofuse.html This is an open-access article distributed under the terms described at http://journals.iucr.org/services/termsofuse.html. |
spellingShingle | Metal-Organic Papers Medlycott, Elaine A. Wang, Jianhua Hanan, Garry S. [2,6-Bis(5-chloropyrimidin-2-yl-κN)pyridine-κN](2,2′:6′,2′′-terpyridine-κ(3) N,N′,N′′)ruthenium(II) bis(hexafluoridophosphate) acetonitrile disolvate |
title | [2,6-Bis(5-chloropyrimidin-2-yl-κN)pyridine-κN](2,2′:6′,2′′-terpyridine-κ(3)
N,N′,N′′)ruthenium(II) bis(hexafluoridophosphate) acetonitrile disolvate |
title_full | [2,6-Bis(5-chloropyrimidin-2-yl-κN)pyridine-κN](2,2′:6′,2′′-terpyridine-κ(3)
N,N′,N′′)ruthenium(II) bis(hexafluoridophosphate) acetonitrile disolvate |
title_fullStr | [2,6-Bis(5-chloropyrimidin-2-yl-κN)pyridine-κN](2,2′:6′,2′′-terpyridine-κ(3)
N,N′,N′′)ruthenium(II) bis(hexafluoridophosphate) acetonitrile disolvate |
title_full_unstemmed | [2,6-Bis(5-chloropyrimidin-2-yl-κN)pyridine-κN](2,2′:6′,2′′-terpyridine-κ(3)
N,N′,N′′)ruthenium(II) bis(hexafluoridophosphate) acetonitrile disolvate |
title_short | [2,6-Bis(5-chloropyrimidin-2-yl-κN)pyridine-κN](2,2′:6′,2′′-terpyridine-κ(3)
N,N′,N′′)ruthenium(II) bis(hexafluoridophosphate) acetonitrile disolvate |
title_sort | [2,6-bis(5-chloropyrimidin-2-yl-κn)pyridine-κn](2,2′:6′,2′′-terpyridine-κ(3)
n,n′,n′′)ruthenium(ii) bis(hexafluoridophosphate) acetonitrile disolvate |
topic | Metal-Organic Papers |
url | https://www.ncbi.nlm.nih.gov/pmc/articles/PMC2960288/ https://www.ncbi.nlm.nih.gov/pubmed/21201294 http://dx.doi.org/10.1107/S1600536807068602 |
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