[2,6-Bis(5-chloro­pyrimidin-2-yl-κN)pyri­dine-κN](2,2′:6′,2′′-terpyridine-κ(3) N,N′,N′′)ruthenium(II) bis­(hexa­fluoridophosphate) acetonitrile disolvate

In the title compound, [Ru(C(13)H(7)Cl(2)N(5))(C(15)H(11)N(3))](PF(6))(2)·2CH(3)CN, the Ru(II) atom is coordinated in a distorted octa­hedral geometry by a tridentate 2,2′:6′,2′′-terpyridine ligand and a tridentate 2,6-bis­(5-chloro­pyrimidin-2-yl)pyridine ligand. Least-squares mean-plane distortion...

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Detalles Bibliográficos
Autores principales: Medlycott, Elaine A., Wang, Jianhua, Hanan, Garry S.
Formato: Texto
Lenguaje:English
Publicado: International Union of Crystallography 2008
Materias:
Metal-Organic Papers
Acceso en línea:https://www.ncbi.nlm.nih.gov/pmc/articles/PMC2960288/
https://www.ncbi.nlm.nih.gov/pubmed/21201294
http://dx.doi.org/10.1107/S1600536807068602
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author Medlycott, Elaine A.
Wang, Jianhua
Hanan, Garry S.
author_facet Medlycott, Elaine A.
Wang, Jianhua
Hanan, Garry S.
author_sort Medlycott, Elaine A.
collection PubMed
description In the title compound, [Ru(C(13)H(7)Cl(2)N(5))(C(15)H(11)N(3))](PF(6))(2)·2CH(3)CN, the Ru(II) atom is coordinated in a distorted octa­hedral geometry by a tridentate 2,2′:6′,2′′-terpyridine ligand and a tridentate 2,6-bis­(5-chloro­pyrimidin-2-yl)pyridine ligand. Least-squares mean-plane distortions of only 1.72 (2) and 2.91 (2)° of the pyrimidyl rings with respect to the central pyridine are observed for the bis­(pyrimid­yl)pyridine-based tridentate ligand, while the distal pyridyl rings of terpyridine twist by 13.43 (7) and 4.68 (9)° away from the central pyridine ring.
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spelling pubmed-29602882010-12-30 [2,6-Bis(5-chloro­pyrimidin-2-yl-κN)pyri­dine-κN](2,2′:6′,2′′-terpyridine-κ(3) N,N′,N′′)ruthenium(II) bis­(hexa­fluoridophosphate) acetonitrile disolvate Medlycott, Elaine A. Wang, Jianhua Hanan, Garry S. Acta Crystallogr Sect E Struct Rep Online Metal-Organic Papers In the title compound, [Ru(C(13)H(7)Cl(2)N(5))(C(15)H(11)N(3))](PF(6))(2)·2CH(3)CN, the Ru(II) atom is coordinated in a distorted octa­hedral geometry by a tridentate 2,2′:6′,2′′-terpyridine ligand and a tridentate 2,6-bis­(5-chloro­pyrimidin-2-yl)pyridine ligand. Least-squares mean-plane distortions of only 1.72 (2) and 2.91 (2)° of the pyrimidyl rings with respect to the central pyridine are observed for the bis­(pyrimid­yl)pyridine-based tridentate ligand, while the distal pyridyl rings of terpyridine twist by 13.43 (7) and 4.68 (9)° away from the central pyridine ring. International Union of Crystallography 2008-01-09 /pmc/articles/PMC2960288/ /pubmed/21201294 http://dx.doi.org/10.1107/S1600536807068602 Text en © International Union of Crystallography 2008 http://journals.iucr.org/services/termsofuse.html This is an open-access article distributed under the terms described at http://journals.iucr.org/services/termsofuse.html.
spellingShingle Metal-Organic Papers
Medlycott, Elaine A.
Wang, Jianhua
Hanan, Garry S.
[2,6-Bis(5-chloro­pyrimidin-2-yl-κN)pyri­dine-κN](2,2′:6′,2′′-terpyridine-κ(3) N,N′,N′′)ruthenium(II) bis­(hexa­fluoridophosphate) acetonitrile disolvate
title [2,6-Bis(5-chloro­pyrimidin-2-yl-κN)pyri­dine-κN](2,2′:6′,2′′-terpyridine-κ(3) N,N′,N′′)ruthenium(II) bis­(hexa­fluoridophosphate) acetonitrile disolvate
title_full [2,6-Bis(5-chloro­pyrimidin-2-yl-κN)pyri­dine-κN](2,2′:6′,2′′-terpyridine-κ(3) N,N′,N′′)ruthenium(II) bis­(hexa­fluoridophosphate) acetonitrile disolvate
title_fullStr [2,6-Bis(5-chloro­pyrimidin-2-yl-κN)pyri­dine-κN](2,2′:6′,2′′-terpyridine-κ(3) N,N′,N′′)ruthenium(II) bis­(hexa­fluoridophosphate) acetonitrile disolvate
title_full_unstemmed [2,6-Bis(5-chloro­pyrimidin-2-yl-κN)pyri­dine-κN](2,2′:6′,2′′-terpyridine-κ(3) N,N′,N′′)ruthenium(II) bis­(hexa­fluoridophosphate) acetonitrile disolvate
title_short [2,6-Bis(5-chloro­pyrimidin-2-yl-κN)pyri­dine-κN](2,2′:6′,2′′-terpyridine-κ(3) N,N′,N′′)ruthenium(II) bis­(hexa­fluoridophosphate) acetonitrile disolvate
title_sort [2,6-bis(5-chloro­pyrimidin-2-yl-κn)pyri­dine-κn](2,2′:6′,2′′-terpyridine-κ(3) n,n′,n′′)ruthenium(ii) bis­(hexa­fluoridophosphate) acetonitrile disolvate
topic Metal-Organic Papers
url https://www.ncbi.nlm.nih.gov/pmc/articles/PMC2960288/
https://www.ncbi.nlm.nih.gov/pubmed/21201294
http://dx.doi.org/10.1107/S1600536807068602
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AT wangjianhua 26bis5chloropyrimidin2ylknpyridinekn2262terpyridinek3nnnrutheniumiibishexafluoridophosphateacetonitriledisolvate
AT hanangarrys 26bis5chloropyrimidin2ylknpyridinekn2262terpyridinek3nnnrutheniumiibishexafluoridophosphateacetonitriledisolvate

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