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catena-Poly[(μ(2)-3-carboxy-5-nitrobenzoato)(μ(3)-5-nitrobenzene-1,3-dicarboxylato)(1,10-phenanthroline)gadolinium(III)]
The crystal structure of the title complex, [Gd(C(8)H(3)NO(6))(C(8)H(4)NO(6))(C(12)H(8)N(2))](n), contains polymeric chains made up of Gd(III) atoms, 1,10-phenanthroline and fully or half-deprotonated 5-nitrobenzene-1,3-dicarboxylic acid (H(2) L) ligands. The Gd(III) atom is coordinated in a dis...
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Formato: | Texto |
Lenguaje: | English |
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International Union of Crystallography
2010
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Acceso en línea: | https://www.ncbi.nlm.nih.gov/pmc/articles/PMC2983181/ https://www.ncbi.nlm.nih.gov/pubmed/21587385 http://dx.doi.org/10.1107/S1600536810035452 |
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author | Wang, Jun Fang, Zhi-Li |
author_facet | Wang, Jun Fang, Zhi-Li |
author_sort | Wang, Jun |
collection | PubMed |
description | The crystal structure of the title complex, [Gd(C(8)H(3)NO(6))(C(8)H(4)NO(6))(C(12)H(8)N(2))](n), contains polymeric chains made up of Gd(III) atoms, 1,10-phenanthroline and fully or half-deprotonated 5-nitrobenzene-1,3-dicarboxylic acid (H(2) L) ligands. The Gd(III) atom is coordinated in a distorted bicapped trigonal-prismatic fashion by six O atoms from two HL (−) and three L (2−) ligands, and by two N atoms from the 1,10-phenanthroline ligand. The L (2−) ligands bridge the Gd–phenanthroline units, forming chains running parallel to [100]. O—H⋯O hydrogen bonding as well as π–π stacking interactions with an interplanar distance of 3.599 (2) Å assemble neighboring polymeric chains. |
format | Text |
id | pubmed-2983181 |
institution | National Center for Biotechnology Information |
language | English |
publishDate | 2010 |
publisher | International Union of Crystallography |
record_format | MEDLINE/PubMed |
spelling | pubmed-29831812010-12-30 catena-Poly[(μ(2)-3-carboxy-5-nitrobenzoato)(μ(3)-5-nitrobenzene-1,3-dicarboxylato)(1,10-phenanthroline)gadolinium(III)] Wang, Jun Fang, Zhi-Li Acta Crystallogr Sect E Struct Rep Online Metal-Organic Papers The crystal structure of the title complex, [Gd(C(8)H(3)NO(6))(C(8)H(4)NO(6))(C(12)H(8)N(2))](n), contains polymeric chains made up of Gd(III) atoms, 1,10-phenanthroline and fully or half-deprotonated 5-nitrobenzene-1,3-dicarboxylic acid (H(2) L) ligands. The Gd(III) atom is coordinated in a distorted bicapped trigonal-prismatic fashion by six O atoms from two HL (−) and three L (2−) ligands, and by two N atoms from the 1,10-phenanthroline ligand. The L (2−) ligands bridge the Gd–phenanthroline units, forming chains running parallel to [100]. O—H⋯O hydrogen bonding as well as π–π stacking interactions with an interplanar distance of 3.599 (2) Å assemble neighboring polymeric chains. International Union of Crystallography 2010-09-08 /pmc/articles/PMC2983181/ /pubmed/21587385 http://dx.doi.org/10.1107/S1600536810035452 Text en © Wang and Fang 2010 http://creativecommons.org/licenses/by/2.0/uk/ This is an open-access article distributed under the terms of the Creative Commons Attribution Licence, which permits unrestricted use, distribution, and reproduction in any medium, provided the original authors and source are cited. |
spellingShingle | Metal-Organic Papers Wang, Jun Fang, Zhi-Li catena-Poly[(μ(2)-3-carboxy-5-nitrobenzoato)(μ(3)-5-nitrobenzene-1,3-dicarboxylato)(1,10-phenanthroline)gadolinium(III)] |
title |
catena-Poly[(μ(2)-3-carboxy-5-nitrobenzoato)(μ(3)-5-nitrobenzene-1,3-dicarboxylato)(1,10-phenanthroline)gadolinium(III)] |
title_full |
catena-Poly[(μ(2)-3-carboxy-5-nitrobenzoato)(μ(3)-5-nitrobenzene-1,3-dicarboxylato)(1,10-phenanthroline)gadolinium(III)] |
title_fullStr |
catena-Poly[(μ(2)-3-carboxy-5-nitrobenzoato)(μ(3)-5-nitrobenzene-1,3-dicarboxylato)(1,10-phenanthroline)gadolinium(III)] |
title_full_unstemmed |
catena-Poly[(μ(2)-3-carboxy-5-nitrobenzoato)(μ(3)-5-nitrobenzene-1,3-dicarboxylato)(1,10-phenanthroline)gadolinium(III)] |
title_short |
catena-Poly[(μ(2)-3-carboxy-5-nitrobenzoato)(μ(3)-5-nitrobenzene-1,3-dicarboxylato)(1,10-phenanthroline)gadolinium(III)] |
title_sort | catena-poly[(μ(2)-3-carboxy-5-nitrobenzoato)(μ(3)-5-nitrobenzene-1,3-dicarboxylato)(1,10-phenanthroline)gadolinium(iii)] |
topic | Metal-Organic Papers |
url | https://www.ncbi.nlm.nih.gov/pmc/articles/PMC2983181/ https://www.ncbi.nlm.nih.gov/pubmed/21587385 http://dx.doi.org/10.1107/S1600536810035452 |
work_keys_str_mv | AT wangjun catenapolym23carboxy5nitrobenzoatom35nitrobenzene13dicarboxylato110phenanthrolinegadoliniumiii AT fangzhili catenapolym23carboxy5nitrobenzoatom35nitrobenzene13dicarboxylato110phenanthrolinegadoliniumiii |