Cargando…

catena-Poly[(μ(2)-3-carb­oxy-5-nitro­benzoato)(μ(3)-5-nitro­benzene-1,3-dicarboxyl­ato)(1,10-phenanthroline)gadolinium(III)]

The crystal structure of the title complex, [Gd(C(8)H(3)NO(6))(C(8)H(4)NO(6))(C(12)H(8)N(2))](n), contains polymeric chains made up of Gd(III) atoms, 1,10-phenanthroline and fully or half-deproton­ated 5-nitro­benzene-1,3-dicarb­oxy­lic acid (H(2) L) ligands. The Gd(III) atom is coordinated in a dis...

Descripción completa

Detalles Bibliográficos
Autores principales: Wang, Jun, Fang, Zhi-Li
Formato: Texto
Lenguaje:English
Publicado: International Union of Crystallography 2010
Materias:
Acceso en línea:https://www.ncbi.nlm.nih.gov/pmc/articles/PMC2983181/
https://www.ncbi.nlm.nih.gov/pubmed/21587385
http://dx.doi.org/10.1107/S1600536810035452
_version_ 1782191819943051264
author Wang, Jun
Fang, Zhi-Li
author_facet Wang, Jun
Fang, Zhi-Li
author_sort Wang, Jun
collection PubMed
description The crystal structure of the title complex, [Gd(C(8)H(3)NO(6))(C(8)H(4)NO(6))(C(12)H(8)N(2))](n), contains polymeric chains made up of Gd(III) atoms, 1,10-phenanthroline and fully or half-deproton­ated 5-nitro­benzene-1,3-dicarb­oxy­lic acid (H(2) L) ligands. The Gd(III) atom is coordinated in a distorted bicapped trigonal-prismatic fashion by six O atoms from two HL (−) and three L (2−) ligands, and by two N atoms from the 1,10-phenanthroline ligand. The L (2−) ligands bridge the Gd–phenanthroline units, forming chains running parallel to [100]. O—H⋯O hydrogen bonding as well as π–π stacking inter­actions with an inter­planar distance of 3.599 (2) Å assemble neighboring polymeric chains.
format Text
id pubmed-2983181
institution National Center for Biotechnology Information
language English
publishDate 2010
publisher International Union of Crystallography
record_format MEDLINE/PubMed
spelling pubmed-29831812010-12-30 catena-Poly[(μ(2)-3-carb­oxy-5-nitro­benzoato)(μ(3)-5-nitro­benzene-1,3-dicarboxyl­ato)(1,10-phenanthroline)gadolinium(III)] Wang, Jun Fang, Zhi-Li Acta Crystallogr Sect E Struct Rep Online Metal-Organic Papers The crystal structure of the title complex, [Gd(C(8)H(3)NO(6))(C(8)H(4)NO(6))(C(12)H(8)N(2))](n), contains polymeric chains made up of Gd(III) atoms, 1,10-phenanthroline and fully or half-deproton­ated 5-nitro­benzene-1,3-dicarb­oxy­lic acid (H(2) L) ligands. The Gd(III) atom is coordinated in a distorted bicapped trigonal-prismatic fashion by six O atoms from two HL (−) and three L (2−) ligands, and by two N atoms from the 1,10-phenanthroline ligand. The L (2−) ligands bridge the Gd–phenanthroline units, forming chains running parallel to [100]. O—H⋯O hydrogen bonding as well as π–π stacking inter­actions with an inter­planar distance of 3.599 (2) Å assemble neighboring polymeric chains. International Union of Crystallography 2010-09-08 /pmc/articles/PMC2983181/ /pubmed/21587385 http://dx.doi.org/10.1107/S1600536810035452 Text en © Wang and Fang 2010 http://creativecommons.org/licenses/by/2.0/uk/ This is an open-access article distributed under the terms of the Creative Commons Attribution Licence, which permits unrestricted use, distribution, and reproduction in any medium, provided the original authors and source are cited.
spellingShingle Metal-Organic Papers
Wang, Jun
Fang, Zhi-Li
catena-Poly[(μ(2)-3-carb­oxy-5-nitro­benzoato)(μ(3)-5-nitro­benzene-1,3-dicarboxyl­ato)(1,10-phenanthroline)gadolinium(III)]
title catena-Poly[(μ(2)-3-carb­oxy-5-nitro­benzoato)(μ(3)-5-nitro­benzene-1,3-dicarboxyl­ato)(1,10-phenanthroline)gadolinium(III)]
title_full catena-Poly[(μ(2)-3-carb­oxy-5-nitro­benzoato)(μ(3)-5-nitro­benzene-1,3-dicarboxyl­ato)(1,10-phenanthroline)gadolinium(III)]
title_fullStr catena-Poly[(μ(2)-3-carb­oxy-5-nitro­benzoato)(μ(3)-5-nitro­benzene-1,3-dicarboxyl­ato)(1,10-phenanthroline)gadolinium(III)]
title_full_unstemmed catena-Poly[(μ(2)-3-carb­oxy-5-nitro­benzoato)(μ(3)-5-nitro­benzene-1,3-dicarboxyl­ato)(1,10-phenanthroline)gadolinium(III)]
title_short catena-Poly[(μ(2)-3-carb­oxy-5-nitro­benzoato)(μ(3)-5-nitro­benzene-1,3-dicarboxyl­ato)(1,10-phenanthroline)gadolinium(III)]
title_sort catena-poly[(μ(2)-3-carb­oxy-5-nitro­benzoato)(μ(3)-5-nitro­benzene-1,3-dicarboxyl­ato)(1,10-phenanthroline)gadolinium(iii)]
topic Metal-Organic Papers
url https://www.ncbi.nlm.nih.gov/pmc/articles/PMC2983181/
https://www.ncbi.nlm.nih.gov/pubmed/21587385
http://dx.doi.org/10.1107/S1600536810035452
work_keys_str_mv AT wangjun catenapolym23carboxy5nitrobenzoatom35nitrobenzene13dicarboxylato110phenanthrolinegadoliniumiii
AT fangzhili catenapolym23carboxy5nitrobenzoatom35nitrobenzene13dicarboxylato110phenanthrolinegadoliniumiii