1-(4-Meth­oxy­benzyl­idene)-4-methyl­thiosemicarbazide

The title compound, C(10)H(13)N(3)OS, was prepared by the reaction of 4-meth­oxy­benzaldehyde and 4-methyl­thio­semicarbazide. The dihedral angle between the benzene ring and the thio­urea unit is 8.64 (7)° and an intra­molecular N—H⋯N hydrogen bond generates an S(5) ring. In the crystal, inversion...

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Detalles Bibliográficos
Autor principal: Li, Yu-Feng
Formato: Texto
Lenguaje:English
Publicado: International Union of Crystallography 2010
Materias:
Organic Papers
Acceso en línea:https://www.ncbi.nlm.nih.gov/pmc/articles/PMC3009075/
https://www.ncbi.nlm.nih.gov/pubmed/21588938
http://dx.doi.org/10.1107/S1600536810038882
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author Li, Yu-Feng
author_facet Li, Yu-Feng
author_sort Li, Yu-Feng
collection PubMed
description The title compound, C(10)H(13)N(3)OS, was prepared by the reaction of 4-meth­oxy­benzaldehyde and 4-methyl­thio­semicarbazide. The dihedral angle between the benzene ring and the thio­urea unit is 8.64 (7)° and an intra­molecular N—H⋯N hydrogen bond generates an S(5) ring. In the crystal, inversion dimers linked by pairs of N—H⋯S hydrogen bonds generate R (2) (2)(8) loops. The dimers are linked into (001) sheets by further N—H⋯S links.
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spelling pubmed-30090752010-12-30 1-(4-Meth­oxy­benzyl­idene)-4-methyl­thiosemicarbazide Li, Yu-Feng Acta Crystallogr Sect E Struct Rep Online Organic Papers The title compound, C(10)H(13)N(3)OS, was prepared by the reaction of 4-meth­oxy­benzaldehyde and 4-methyl­thio­semicarbazide. The dihedral angle between the benzene ring and the thio­urea unit is 8.64 (7)° and an intra­molecular N—H⋯N hydrogen bond generates an S(5) ring. In the crystal, inversion dimers linked by pairs of N—H⋯S hydrogen bonds generate R (2) (2)(8) loops. The dimers are linked into (001) sheets by further N—H⋯S links. International Union of Crystallography 2010-10-09 /pmc/articles/PMC3009075/ /pubmed/21588938 http://dx.doi.org/10.1107/S1600536810038882 Text en © Yu-Feng Li 2010 http://creativecommons.org/licenses/by/2.0/uk/ This is an open-access article distributed under the terms of the Creative Commons Attribution Licence, which permits unrestricted use, distribution, and reproduction in any medium, provided the original authors and source are cited.
spellingShingle Organic Papers
Li, Yu-Feng
1-(4-Meth­oxy­benzyl­idene)-4-methyl­thiosemicarbazide
title 1-(4-Meth­oxy­benzyl­idene)-4-methyl­thiosemicarbazide
title_full 1-(4-Meth­oxy­benzyl­idene)-4-methyl­thiosemicarbazide
title_fullStr 1-(4-Meth­oxy­benzyl­idene)-4-methyl­thiosemicarbazide
title_full_unstemmed 1-(4-Meth­oxy­benzyl­idene)-4-methyl­thiosemicarbazide
title_short 1-(4-Meth­oxy­benzyl­idene)-4-methyl­thiosemicarbazide
title_sort 1-(4-meth­oxy­benzyl­idene)-4-methyl­thiosemicarbazide
topic Organic Papers
url https://www.ncbi.nlm.nih.gov/pmc/articles/PMC3009075/
https://www.ncbi.nlm.nih.gov/pubmed/21588938
http://dx.doi.org/10.1107/S1600536810038882
work_keys_str_mv AT liyufeng 14methoxybenzylidene4methylthiosemicarbazide

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