[1,5-Bis(2-meth­oxy­phen­yl)thio­carbazo­nato-κ(2) N (1),S]phenyl­mercury(II)

The title compound, [Hg(C(6)H(5))(C(15)H(15)N(4)O(2)S)], shows the metal–phenyl moiety coordinated out of plane with the thio­carbazo­nate ligand by 43.84 (6)°. Important geometrical parameters include Hg—S = 2.3653 (10) Å, Hg—C = 2.058 (4) Å and S—Hg—C = 179.06 (11)°. There is a weak coordination o...

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Detalles Bibliográficos
Autores principales: von Eschwege, Karel, Muller, Fabian, Muller, Alfred
Formato: Online Artículo Texto
Lenguaje:English
Publicado: International Union of Crystallography 2011
Materias:
Metal-Organic Papers
Acceso en línea:https://www.ncbi.nlm.nih.gov/pmc/articles/PMC3238710/
https://www.ncbi.nlm.nih.gov/pubmed/22199587
http://dx.doi.org/10.1107/S1600536811049099
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author von Eschwege, Karel
Muller, Fabian
Muller, Alfred
author_facet von Eschwege, Karel
Muller, Fabian
Muller, Alfred
author_sort von Eschwege, Karel
collection PubMed
description The title compound, [Hg(C(6)H(5))(C(15)H(15)N(4)O(2)S)], shows the metal–phenyl moiety coordinated out of plane with the thio­carbazo­nate ligand by 43.84 (6)°. Important geometrical parameters include Hg—S = 2.3653 (10) Å, Hg—C = 2.058 (4) Å and S—Hg—C = 179.06 (11)°. There is a weak coordination of an N atom of the ligand to Hg [Hg—N = 2.725 (3) Å]. S⋯Hg inter­actions[3.2928 (10) Å] form chains along [001], stabilizing the crystal structure.
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spelling pubmed-32387102011-12-23 [1,5-Bis(2-meth­oxy­phen­yl)thio­carbazo­nato-κ(2) N (1),S]phenyl­mercury(II) von Eschwege, Karel Muller, Fabian Muller, Alfred Acta Crystallogr Sect E Struct Rep Online Metal-Organic Papers The title compound, [Hg(C(6)H(5))(C(15)H(15)N(4)O(2)S)], shows the metal–phenyl moiety coordinated out of plane with the thio­carbazo­nate ligand by 43.84 (6)°. Important geometrical parameters include Hg—S = 2.3653 (10) Å, Hg—C = 2.058 (4) Å and S—Hg—C = 179.06 (11)°. There is a weak coordination of an N atom of the ligand to Hg [Hg—N = 2.725 (3) Å]. S⋯Hg inter­actions[3.2928 (10) Å] form chains along [001], stabilizing the crystal structure. International Union of Crystallography 2011-11-23 /pmc/articles/PMC3238710/ /pubmed/22199587 http://dx.doi.org/10.1107/S1600536811049099 Text en © Eschwege et al. 2011 http://creativecommons.org/licenses/by/2.0/uk/ This is an open-access article distributed under the terms of the Creative Commons Attribution Licence, which permits unrestricted use, distribution, and reproduction in any medium, provided the original authors and source are cited.
spellingShingle Metal-Organic Papers
von Eschwege, Karel
Muller, Fabian
Muller, Alfred
[1,5-Bis(2-meth­oxy­phen­yl)thio­carbazo­nato-κ(2) N (1),S]phenyl­mercury(II)
title [1,5-Bis(2-meth­oxy­phen­yl)thio­carbazo­nato-κ(2) N (1),S]phenyl­mercury(II)
title_full [1,5-Bis(2-meth­oxy­phen­yl)thio­carbazo­nato-κ(2) N (1),S]phenyl­mercury(II)
title_fullStr [1,5-Bis(2-meth­oxy­phen­yl)thio­carbazo­nato-κ(2) N (1),S]phenyl­mercury(II)
title_full_unstemmed [1,5-Bis(2-meth­oxy­phen­yl)thio­carbazo­nato-κ(2) N (1),S]phenyl­mercury(II)
title_short [1,5-Bis(2-meth­oxy­phen­yl)thio­carbazo­nato-κ(2) N (1),S]phenyl­mercury(II)
title_sort [1,5-bis(2-meth­oxy­phen­yl)thio­carbazo­nato-κ(2) n (1),s]phenyl­mercury(ii)
topic Metal-Organic Papers
url https://www.ncbi.nlm.nih.gov/pmc/articles/PMC3238710/
https://www.ncbi.nlm.nih.gov/pubmed/22199587
http://dx.doi.org/10.1107/S1600536811049099
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AT mullerfabian 15bis2methoxyphenylthiocarbazonatok2n1sphenylmercuryii
AT mulleralfred 15bis2methoxyphenylthiocarbazonatok2n1sphenylmercuryii

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