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4-Methyl-N-(4-methyl­phenyl­sulfon­yl)-N-[4-(4-methyl­phen­yl)-1,3-thia­zol-2-yl]benzene­sulfonamide

There are two independent mol­ecules in the asymmetric unit of the title compound, C(24)H(22)N(2)O(4)S(3). In each, the sulfonamide N atoms reveal nearly a trigonal-planar geometry with two S atoms of the O=S=O groups and one C atom of the thia­zole ring; the angles around the N atoms are between 11...

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Detalles Bibliográficos
Autores principales: Carballo, Rubén M., Hernández-Ortega, Simón, Padilla-Montaño, Nayely, Reyes-Martínez, Reyna, Mirón-López, Gumersindo
Formato: Online Artículo Texto
Lenguaje:English
Publicado: International Union of Crystallography 2013
Materias:
Acceso en línea:https://www.ncbi.nlm.nih.gov/pmc/articles/PMC3914048/
https://www.ncbi.nlm.nih.gov/pubmed/24526999
http://dx.doi.org/10.1107/S1600536813032145
Descripción
Sumario:There are two independent mol­ecules in the asymmetric unit of the title compound, C(24)H(22)N(2)O(4)S(3). In each, the sulfonamide N atoms reveal nearly a trigonal-planar geometry with two S atoms of the O=S=O groups and one C atom of the thia­zole ring; the angles around the N atoms are between 117.00 (13) and 123.86 (9)°. The methyl­phenyl­sulfonyl groups are in anti conformations, forming dihedral angles of 78.00 (7)/72.53 (5) and 77.09 (6)/71.50 (7)° with the trigonal S—N—S planes in the two mol­ecules. The thia­zole groups are rotated around the C—N bonds and are almost perpendicular to the S—N—S plane [dihedral angles of 78.00 (7)/72.53 (5) and 77.09 (6)/71.50 (7)°]. In the crystal, pairs of C—H⋯O inter­actions, with the O atoms of the sulfonamide groups as acceptors, link each of the independent mol­ecules into inversion dimers.