Bis(μ(2)-di­phenyl­phosphinamide-κ(2) O:O)bis­[bis(di­phenyl­phosphinamide-κO)lithium] dichloride aceto­nitrile disolvate

The asymmetric unit of the title compound, [Li(2)(C(12)H(12)NOP)(6)]Cl(2)·2CH(3)CN, contains one-half of the centrosymmetric dication, one chloride anion and one aceto­nitrile solvent mol­ecule. Each Li atom is coordinated by four O atoms [Li—O 1.891 (3) and 2.025 (3) Å] from the four di­phenyl­phos...

Descripción completa

Detalles Bibliográficos
Autores principales: Li, Ai-Hong, Han, Jun-Ping, Li, Jing
Formato: Online Artículo Texto
Lenguaje:English
Publicado: International Union of Crystallography 2014
Materias:
Acceso en línea:https://www.ncbi.nlm.nih.gov/pmc/articles/PMC4051072/
https://www.ncbi.nlm.nih.gov/pubmed/24940208
http://dx.doi.org/10.1107/S1600536814011076
_version_ 1782320053060894720
author Li, Ai-Hong
Han, Jun-Ping
Li, Jing
author_facet Li, Ai-Hong
Han, Jun-Ping
Li, Jing
author_sort Li, Ai-Hong
collection PubMed
description The asymmetric unit of the title compound, [Li(2)(C(12)H(12)NOP)(6)]Cl(2)·2CH(3)CN, contains one-half of the centrosymmetric dication, one chloride anion and one aceto­nitrile solvent mol­ecule. Each Li atom is coordinated by four O atoms [Li—O 1.891 (3) and 2.025 (3) Å] from the four di­phenyl­phosphinamide ligands in a distorted tetra­hedral geometry. In the crystal, weak N—H⋯Cl hydrogen bonds link the anions and dications into columns extending along [100].
format Online
Article
Text
id pubmed-4051072
institution National Center for Biotechnology Information
language English
publishDate 2014
publisher International Union of Crystallography
record_format MEDLINE/PubMed
spelling pubmed-40510722014-06-17 Bis(μ(2)-di­phenyl­phosphinamide-κ(2) O:O)bis­[bis(di­phenyl­phosphinamide-κO)lithium] dichloride aceto­nitrile disolvate Li, Ai-Hong Han, Jun-Ping Li, Jing Acta Crystallogr Sect E Struct Rep Online Metal-Organic Papers The asymmetric unit of the title compound, [Li(2)(C(12)H(12)NOP)(6)]Cl(2)·2CH(3)CN, contains one-half of the centrosymmetric dication, one chloride anion and one aceto­nitrile solvent mol­ecule. Each Li atom is coordinated by four O atoms [Li—O 1.891 (3) and 2.025 (3) Å] from the four di­phenyl­phosphinamide ligands in a distorted tetra­hedral geometry. In the crystal, weak N—H⋯Cl hydrogen bonds link the anions and dications into columns extending along [100]. International Union of Crystallography 2014-05-21 /pmc/articles/PMC4051072/ /pubmed/24940208 http://dx.doi.org/10.1107/S1600536814011076 Text en © Li et al. 2014 http://creativecommons.org/licenses/by/2.0/uk/ This is an open-access article distributed under the terms of the Creative Commons Attribution Licence, which permits unrestricted use, distribution, and reproduction in any medium, provided the original authors and source are cited.
spellingShingle Metal-Organic Papers
Li, Ai-Hong
Han, Jun-Ping
Li, Jing
Bis(μ(2)-di­phenyl­phosphinamide-κ(2) O:O)bis­[bis(di­phenyl­phosphinamide-κO)lithium] dichloride aceto­nitrile disolvate
title Bis(μ(2)-di­phenyl­phosphinamide-κ(2) O:O)bis­[bis(di­phenyl­phosphinamide-κO)lithium] dichloride aceto­nitrile disolvate
title_full Bis(μ(2)-di­phenyl­phosphinamide-κ(2) O:O)bis­[bis(di­phenyl­phosphinamide-κO)lithium] dichloride aceto­nitrile disolvate
title_fullStr Bis(μ(2)-di­phenyl­phosphinamide-κ(2) O:O)bis­[bis(di­phenyl­phosphinamide-κO)lithium] dichloride aceto­nitrile disolvate
title_full_unstemmed Bis(μ(2)-di­phenyl­phosphinamide-κ(2) O:O)bis­[bis(di­phenyl­phosphinamide-κO)lithium] dichloride aceto­nitrile disolvate
title_short Bis(μ(2)-di­phenyl­phosphinamide-κ(2) O:O)bis­[bis(di­phenyl­phosphinamide-κO)lithium] dichloride aceto­nitrile disolvate
title_sort bis(μ(2)-di­phenyl­phosphinamide-κ(2) o:o)bis­[bis(di­phenyl­phosphinamide-κo)lithium] dichloride aceto­nitrile disolvate
topic Metal-Organic Papers
url https://www.ncbi.nlm.nih.gov/pmc/articles/PMC4051072/
https://www.ncbi.nlm.nih.gov/pubmed/24940208
http://dx.doi.org/10.1107/S1600536814011076
work_keys_str_mv AT liaihong bism2diphenylphosphinamidek2oobisbisdiphenylphosphinamidekolithiumdichlorideacetonitriledisolvate
AT hanjunping bism2diphenylphosphinamidek2oobisbisdiphenylphosphinamidekolithiumdichlorideacetonitriledisolvate
AT lijing bism2diphenylphosphinamidek2oobisbisdiphenylphosphinamidekolithiumdichlorideacetonitriledisolvate