Bis(μ(2)-diphenylphosphinamide-κ(2) O:O)bis[bis(diphenylphosphinamide-κO)lithium] dichloride acetonitrile disolvate
The asymmetric unit of the title compound, [Li(2)(C(12)H(12)NOP)(6)]Cl(2)·2CH(3)CN, contains one-half of the centrosymmetric dication, one chloride anion and one acetonitrile solvent molecule. Each Li atom is coordinated by four O atoms [Li—O 1.891 (3) and 2.025 (3) Å] from the four diphenylphos...
Autores principales: | , , |
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Formato: | Online Artículo Texto |
Lenguaje: | English |
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International Union of Crystallography
2014
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Acceso en línea: | https://www.ncbi.nlm.nih.gov/pmc/articles/PMC4051072/ https://www.ncbi.nlm.nih.gov/pubmed/24940208 http://dx.doi.org/10.1107/S1600536814011076 |
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author | Li, Ai-Hong Han, Jun-Ping Li, Jing |
author_facet | Li, Ai-Hong Han, Jun-Ping Li, Jing |
author_sort | Li, Ai-Hong |
collection | PubMed |
description | The asymmetric unit of the title compound, [Li(2)(C(12)H(12)NOP)(6)]Cl(2)·2CH(3)CN, contains one-half of the centrosymmetric dication, one chloride anion and one acetonitrile solvent molecule. Each Li atom is coordinated by four O atoms [Li—O 1.891 (3) and 2.025 (3) Å] from the four diphenylphosphinamide ligands in a distorted tetrahedral geometry. In the crystal, weak N—H⋯Cl hydrogen bonds link the anions and dications into columns extending along [100]. |
format | Online Article Text |
id | pubmed-4051072 |
institution | National Center for Biotechnology Information |
language | English |
publishDate | 2014 |
publisher | International Union of Crystallography |
record_format | MEDLINE/PubMed |
spelling | pubmed-40510722014-06-17 Bis(μ(2)-diphenylphosphinamide-κ(2) O:O)bis[bis(diphenylphosphinamide-κO)lithium] dichloride acetonitrile disolvate Li, Ai-Hong Han, Jun-Ping Li, Jing Acta Crystallogr Sect E Struct Rep Online Metal-Organic Papers The asymmetric unit of the title compound, [Li(2)(C(12)H(12)NOP)(6)]Cl(2)·2CH(3)CN, contains one-half of the centrosymmetric dication, one chloride anion and one acetonitrile solvent molecule. Each Li atom is coordinated by four O atoms [Li—O 1.891 (3) and 2.025 (3) Å] from the four diphenylphosphinamide ligands in a distorted tetrahedral geometry. In the crystal, weak N—H⋯Cl hydrogen bonds link the anions and dications into columns extending along [100]. International Union of Crystallography 2014-05-21 /pmc/articles/PMC4051072/ /pubmed/24940208 http://dx.doi.org/10.1107/S1600536814011076 Text en © Li et al. 2014 http://creativecommons.org/licenses/by/2.0/uk/ This is an open-access article distributed under the terms of the Creative Commons Attribution Licence, which permits unrestricted use, distribution, and reproduction in any medium, provided the original authors and source are cited. |
spellingShingle | Metal-Organic Papers Li, Ai-Hong Han, Jun-Ping Li, Jing Bis(μ(2)-diphenylphosphinamide-κ(2) O:O)bis[bis(diphenylphosphinamide-κO)lithium] dichloride acetonitrile disolvate |
title | Bis(μ(2)-diphenylphosphinamide-κ(2)
O:O)bis[bis(diphenylphosphinamide-κO)lithium] dichloride acetonitrile disolvate |
title_full | Bis(μ(2)-diphenylphosphinamide-κ(2)
O:O)bis[bis(diphenylphosphinamide-κO)lithium] dichloride acetonitrile disolvate |
title_fullStr | Bis(μ(2)-diphenylphosphinamide-κ(2)
O:O)bis[bis(diphenylphosphinamide-κO)lithium] dichloride acetonitrile disolvate |
title_full_unstemmed | Bis(μ(2)-diphenylphosphinamide-κ(2)
O:O)bis[bis(diphenylphosphinamide-κO)lithium] dichloride acetonitrile disolvate |
title_short | Bis(μ(2)-diphenylphosphinamide-κ(2)
O:O)bis[bis(diphenylphosphinamide-κO)lithium] dichloride acetonitrile disolvate |
title_sort | bis(μ(2)-diphenylphosphinamide-κ(2)
o:o)bis[bis(diphenylphosphinamide-κo)lithium] dichloride acetonitrile disolvate |
topic | Metal-Organic Papers |
url | https://www.ncbi.nlm.nih.gov/pmc/articles/PMC4051072/ https://www.ncbi.nlm.nih.gov/pubmed/24940208 http://dx.doi.org/10.1107/S1600536814011076 |
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