Crystal structure of (aceto­nitrile-κN)iodido­(2-(naphthalen-1-yl)-6-{1-[(2,4,6-tri­methyl­phen­yl)imino]ethyl}­pyridine-κ(2) N,N′)copper(I)

In the mononuclear title complex, [CuI(C(2)H(3)N)(C(26)H(24)N(2))], the Cu(I) ion has a distorted tetra­hedral coordination environment, defined by two N atoms of the chelating 2-(naphthalen-1-yl)-6-[(2,4,6-tri­methyl­phen­yl)imino]­pyridine ligand, one N atom of an aceto­nitrile ligand and one iodi...

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Detalles Bibliográficos
Autores principales: Al-Najjar, Nada, Solan, Gregory A., Singh, Kuldip
Formato: Online Artículo Texto
Lenguaje:English
Publicado: International Union of Crystallography 2016
Materias:
Acceso en línea:https://www.ncbi.nlm.nih.gov/pmc/articles/PMC5137624/
https://www.ncbi.nlm.nih.gov/pubmed/27980846
http://dx.doi.org/10.1107/S2056989016018685
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author Al-Najjar, Nada
Solan, Gregory A.
Singh, Kuldip
author_facet Al-Najjar, Nada
Solan, Gregory A.
Singh, Kuldip
author_sort Al-Najjar, Nada
collection PubMed
description In the mononuclear title complex, [CuI(C(2)H(3)N)(C(26)H(24)N(2))], the Cu(I) ion has a distorted tetra­hedral coordination environment, defined by two N atoms of the chelating 2-(naphthalen-1-yl)-6-[(2,4,6-tri­methyl­phen­yl)imino]­pyridine ligand, one N atom of an aceto­nitrile ligand and one iodide ligand. Within the complex, there are weak intra­molecular C—H⋯N hydrogen bonds, while weak inter­molecular C—H⋯I inter­actions between complex mol­ecules, help to facilitate a three-dimensional network.
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spelling pubmed-51376242016-12-15 Crystal structure of (aceto­nitrile-κN)iodido­(2-(naphthalen-1-yl)-6-{1-[(2,4,6-tri­methyl­phen­yl)imino]ethyl}­pyridine-κ(2) N,N′)copper(I) Al-Najjar, Nada Solan, Gregory A. Singh, Kuldip Acta Crystallogr E Crystallogr Commun Research Communications In the mononuclear title complex, [CuI(C(2)H(3)N)(C(26)H(24)N(2))], the Cu(I) ion has a distorted tetra­hedral coordination environment, defined by two N atoms of the chelating 2-(naphthalen-1-yl)-6-[(2,4,6-tri­methyl­phen­yl)imino]­pyridine ligand, one N atom of an aceto­nitrile ligand and one iodide ligand. Within the complex, there are weak intra­molecular C—H⋯N hydrogen bonds, while weak inter­molecular C—H⋯I inter­actions between complex mol­ecules, help to facilitate a three-dimensional network. International Union of Crystallography 2016-11-29 /pmc/articles/PMC5137624/ /pubmed/27980846 http://dx.doi.org/10.1107/S2056989016018685 Text en © Al-Najjar et al. 2016 http://creativecommons.org/licenses/by/2.0/uk/ This is an open-access article distributed under the terms of the Creative Commons Attribution Licence, which permits unrestricted use, distribution, and reproduction in any medium, provided the original authors and source are cited.
spellingShingle Research Communications
Al-Najjar, Nada
Solan, Gregory A.
Singh, Kuldip
Crystal structure of (aceto­nitrile-κN)iodido­(2-(naphthalen-1-yl)-6-{1-[(2,4,6-tri­methyl­phen­yl)imino]ethyl}­pyridine-κ(2) N,N′)copper(I)
title Crystal structure of (aceto­nitrile-κN)iodido­(2-(naphthalen-1-yl)-6-{1-[(2,4,6-tri­methyl­phen­yl)imino]ethyl}­pyridine-κ(2) N,N′)copper(I)
title_full Crystal structure of (aceto­nitrile-κN)iodido­(2-(naphthalen-1-yl)-6-{1-[(2,4,6-tri­methyl­phen­yl)imino]ethyl}­pyridine-κ(2) N,N′)copper(I)
title_fullStr Crystal structure of (aceto­nitrile-κN)iodido­(2-(naphthalen-1-yl)-6-{1-[(2,4,6-tri­methyl­phen­yl)imino]ethyl}­pyridine-κ(2) N,N′)copper(I)
title_full_unstemmed Crystal structure of (aceto­nitrile-κN)iodido­(2-(naphthalen-1-yl)-6-{1-[(2,4,6-tri­methyl­phen­yl)imino]ethyl}­pyridine-κ(2) N,N′)copper(I)
title_short Crystal structure of (aceto­nitrile-κN)iodido­(2-(naphthalen-1-yl)-6-{1-[(2,4,6-tri­methyl­phen­yl)imino]ethyl}­pyridine-κ(2) N,N′)copper(I)
title_sort crystal structure of (aceto­nitrile-κn)iodido­(2-(naphthalen-1-yl)-6-{1-[(2,4,6-tri­methyl­phen­yl)imino]ethyl}­pyridine-κ(2) n,n′)copper(i)
topic Research Communications
url https://www.ncbi.nlm.nih.gov/pmc/articles/PMC5137624/
https://www.ncbi.nlm.nih.gov/pubmed/27980846
http://dx.doi.org/10.1107/S2056989016018685
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