Crystal structure of (acetonitrile-κN)iodido(2-(naphthalen-1-yl)-6-{1-[(2,4,6-trimethylphenyl)imino]ethyl}pyridine-κ(2) N,N′)copper(I)
In the mononuclear title complex, [CuI(C(2)H(3)N)(C(26)H(24)N(2))], the Cu(I) ion has a distorted tetrahedral coordination environment, defined by two N atoms of the chelating 2-(naphthalen-1-yl)-6-[(2,4,6-trimethylphenyl)imino]pyridine ligand, one N atom of an acetonitrile ligand and one iodi...
Autores principales: | , , |
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Formato: | Online Artículo Texto |
Lenguaje: | English |
Publicado: |
International Union of Crystallography
2016
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Acceso en línea: | https://www.ncbi.nlm.nih.gov/pmc/articles/PMC5137624/ https://www.ncbi.nlm.nih.gov/pubmed/27980846 http://dx.doi.org/10.1107/S2056989016018685 |
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author | Al-Najjar, Nada Solan, Gregory A. Singh, Kuldip |
author_facet | Al-Najjar, Nada Solan, Gregory A. Singh, Kuldip |
author_sort | Al-Najjar, Nada |
collection | PubMed |
description | In the mononuclear title complex, [CuI(C(2)H(3)N)(C(26)H(24)N(2))], the Cu(I) ion has a distorted tetrahedral coordination environment, defined by two N atoms of the chelating 2-(naphthalen-1-yl)-6-[(2,4,6-trimethylphenyl)imino]pyridine ligand, one N atom of an acetonitrile ligand and one iodide ligand. Within the complex, there are weak intramolecular C—H⋯N hydrogen bonds, while weak intermolecular C—H⋯I interactions between complex molecules, help to facilitate a three-dimensional network. |
format | Online Article Text |
id | pubmed-5137624 |
institution | National Center for Biotechnology Information |
language | English |
publishDate | 2016 |
publisher | International Union of Crystallography |
record_format | MEDLINE/PubMed |
spelling | pubmed-51376242016-12-15 Crystal structure of (acetonitrile-κN)iodido(2-(naphthalen-1-yl)-6-{1-[(2,4,6-trimethylphenyl)imino]ethyl}pyridine-κ(2) N,N′)copper(I) Al-Najjar, Nada Solan, Gregory A. Singh, Kuldip Acta Crystallogr E Crystallogr Commun Research Communications In the mononuclear title complex, [CuI(C(2)H(3)N)(C(26)H(24)N(2))], the Cu(I) ion has a distorted tetrahedral coordination environment, defined by two N atoms of the chelating 2-(naphthalen-1-yl)-6-[(2,4,6-trimethylphenyl)imino]pyridine ligand, one N atom of an acetonitrile ligand and one iodide ligand. Within the complex, there are weak intramolecular C—H⋯N hydrogen bonds, while weak intermolecular C—H⋯I interactions between complex molecules, help to facilitate a three-dimensional network. International Union of Crystallography 2016-11-29 /pmc/articles/PMC5137624/ /pubmed/27980846 http://dx.doi.org/10.1107/S2056989016018685 Text en © Al-Najjar et al. 2016 http://creativecommons.org/licenses/by/2.0/uk/ This is an open-access article distributed under the terms of the Creative Commons Attribution Licence, which permits unrestricted use, distribution, and reproduction in any medium, provided the original authors and source are cited. |
spellingShingle | Research Communications Al-Najjar, Nada Solan, Gregory A. Singh, Kuldip Crystal structure of (acetonitrile-κN)iodido(2-(naphthalen-1-yl)-6-{1-[(2,4,6-trimethylphenyl)imino]ethyl}pyridine-κ(2) N,N′)copper(I) |
title | Crystal structure of (acetonitrile-κN)iodido(2-(naphthalen-1-yl)-6-{1-[(2,4,6-trimethylphenyl)imino]ethyl}pyridine-κ(2)
N,N′)copper(I) |
title_full | Crystal structure of (acetonitrile-κN)iodido(2-(naphthalen-1-yl)-6-{1-[(2,4,6-trimethylphenyl)imino]ethyl}pyridine-κ(2)
N,N′)copper(I) |
title_fullStr | Crystal structure of (acetonitrile-κN)iodido(2-(naphthalen-1-yl)-6-{1-[(2,4,6-trimethylphenyl)imino]ethyl}pyridine-κ(2)
N,N′)copper(I) |
title_full_unstemmed | Crystal structure of (acetonitrile-κN)iodido(2-(naphthalen-1-yl)-6-{1-[(2,4,6-trimethylphenyl)imino]ethyl}pyridine-κ(2)
N,N′)copper(I) |
title_short | Crystal structure of (acetonitrile-κN)iodido(2-(naphthalen-1-yl)-6-{1-[(2,4,6-trimethylphenyl)imino]ethyl}pyridine-κ(2)
N,N′)copper(I) |
title_sort | crystal structure of (acetonitrile-κn)iodido(2-(naphthalen-1-yl)-6-{1-[(2,4,6-trimethylphenyl)imino]ethyl}pyridine-κ(2)
n,n′)copper(i) |
topic | Research Communications |
url | https://www.ncbi.nlm.nih.gov/pmc/articles/PMC5137624/ https://www.ncbi.nlm.nih.gov/pubmed/27980846 http://dx.doi.org/10.1107/S2056989016018685 |
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