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Efficient and New Production Methods of Chemicals and Liquid Fuels by Carbon Monoxide Hydrogenation

[Image: see text] Carbon monoxide (CO) hydrogenation is an important step for efficient utilization of carbon resources in C1 (one carbon) chemistry. Over recent years, this direction has been a hot research area in academia and industry and has also been one of the most challenging routes for the n...

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Autores principales: Du, Ce, Lu, Peng, Tsubaki, Noritatsu
Formato: Online Artículo Texto
Lenguaje:English
Publicado: American Chemical Society 2019
Acceso en línea:https://www.ncbi.nlm.nih.gov/pmc/articles/PMC6963990/
https://www.ncbi.nlm.nih.gov/pubmed/31956750
http://dx.doi.org/10.1021/acsomega.9b03577
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author Du, Ce
Lu, Peng
Tsubaki, Noritatsu
author_facet Du, Ce
Lu, Peng
Tsubaki, Noritatsu
author_sort Du, Ce
collection PubMed
description [Image: see text] Carbon monoxide (CO) hydrogenation is an important step for efficient utilization of carbon resources in C1 (one carbon) chemistry. Over recent years, this direction has been a hot research area in academia and industry and has also been one of the most challenging routes for the nonoil carbon resources utilization process. A large number of novel reaction routes and catalysts have been studied and reported. Efficient activation and directional conversion of CO are key aspects in the process of CO utilization. Furthermore, effectively activating C–O and C–C bond formation as well as controlling carbon chain growth is the current technical bottleneck of CO hydrogenation. This mini-review introduces the latest research progress for different catalyst systems and processes in CO hydrogenation and analyzes the factors that control the performance of catalysts in different reaction systems. Here, much focus is put on the synthesis of long-chain hydrocarbons, light olefins, C(2+) oxygenates, and aromatics, essentially in comparison with the previous reports. Finally, the present challenges and future research directions have been discussed.
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spelling pubmed-69639902020-01-17 Efficient and New Production Methods of Chemicals and Liquid Fuels by Carbon Monoxide Hydrogenation Du, Ce Lu, Peng Tsubaki, Noritatsu ACS Omega [Image: see text] Carbon monoxide (CO) hydrogenation is an important step for efficient utilization of carbon resources in C1 (one carbon) chemistry. Over recent years, this direction has been a hot research area in academia and industry and has also been one of the most challenging routes for the nonoil carbon resources utilization process. A large number of novel reaction routes and catalysts have been studied and reported. Efficient activation and directional conversion of CO are key aspects in the process of CO utilization. Furthermore, effectively activating C–O and C–C bond formation as well as controlling carbon chain growth is the current technical bottleneck of CO hydrogenation. This mini-review introduces the latest research progress for different catalyst systems and processes in CO hydrogenation and analyzes the factors that control the performance of catalysts in different reaction systems. Here, much focus is put on the synthesis of long-chain hydrocarbons, light olefins, C(2+) oxygenates, and aromatics, essentially in comparison with the previous reports. Finally, the present challenges and future research directions have been discussed. American Chemical Society 2019-12-18 /pmc/articles/PMC6963990/ /pubmed/31956750 http://dx.doi.org/10.1021/acsomega.9b03577 Text en Copyright © 2019 American Chemical Society This is an open access article published under an ACS AuthorChoice License (http://pubs.acs.org/page/policy/authorchoice_termsofuse.html) , which permits copying and redistribution of the article or any adaptations for non-commercial purposes.
spellingShingle Du, Ce
Lu, Peng
Tsubaki, Noritatsu
Efficient and New Production Methods of Chemicals and Liquid Fuels by Carbon Monoxide Hydrogenation
title Efficient and New Production Methods of Chemicals and Liquid Fuels by Carbon Monoxide Hydrogenation
title_full Efficient and New Production Methods of Chemicals and Liquid Fuels by Carbon Monoxide Hydrogenation
title_fullStr Efficient and New Production Methods of Chemicals and Liquid Fuels by Carbon Monoxide Hydrogenation
title_full_unstemmed Efficient and New Production Methods of Chemicals and Liquid Fuels by Carbon Monoxide Hydrogenation
title_short Efficient and New Production Methods of Chemicals and Liquid Fuels by Carbon Monoxide Hydrogenation
title_sort efficient and new production methods of chemicals and liquid fuels by carbon monoxide hydrogenation
url https://www.ncbi.nlm.nih.gov/pmc/articles/PMC6963990/
https://www.ncbi.nlm.nih.gov/pubmed/31956750
http://dx.doi.org/10.1021/acsomega.9b03577
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