Aluminum-catalyzed tunable halodefluorination of trifluoromethyl- and difluoroalkyl-substituted olefins

Herein, we report unprecedented aluminum-catalyzed halodefluorination reactions of trifluoromethyl- and difluoroalkyl-substituted olefins with bromo- or chlorotrimethylsilane. The interesting feature of these reactions is that one, two, or three fluorine atoms can be selectively replaced with bromin...

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Detalles Bibliográficos
Autores principales: Liu, Zhong, Tu, Xian-Shuang, Guo, Le-Tao, Wang, Xiao-Chen
Formato: Online Artículo Texto
Lenguaje:English
Publicado: The Royal Society of Chemistry 2020
Materias:
Acceso en línea:https://www.ncbi.nlm.nih.gov/pmc/articles/PMC8162833/
https://www.ncbi.nlm.nih.gov/pubmed/34094400
http://dx.doi.org/10.1039/d0sc03883k