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Labile Base‐Stabilized Silyliumylidene Ions. Non‐Metallic Species Capable of Activating Multiple Small Molecules

Several base‐stabilized silyliumylidene ions (2 and 3) with different ligands were synthesized. Their behaviour appeared strongly dependent on the nature of ligand. Indeed, in contrast to the poorly reactive silyliumylidene ions 3  c,d stabilized by strongly donating ligands (DMAP, NHC), the silylen...

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Detalles Bibliográficos
Autores principales: Nougué, Raphaël, Takahashi, Shintaro, Dajnak, Aymeric, Maerten, Eddy, Baceiredo, Antoine, Saffon‐Merceron, Nathalie, Branchadell, Vicenç, Kato, Tsuyoshi
Formato: Online Artículo Texto
Lenguaje:English
Publicado: John Wiley and Sons Inc. 2022
Materias:
Acceso en línea:https://www.ncbi.nlm.nih.gov/pmc/articles/PMC10092131/
https://www.ncbi.nlm.nih.gov/pubmed/36074891
http://dx.doi.org/10.1002/chem.202202037