Selective synthesis of spirobiindanes, alkenyl chlorides, and monofluoroalkenes from unactivated gem-difluoroalkanes controlled by aluminum-based Lewis acids

The highly selective synthesis of spirobiindanes, alkenyl chlorides, and monofluoroalkenes via the cleavage of inert C(sp(3))–F bonds in unactivated gem-difluoroalkanes using readily available and inexpensive aluminum-based Lewis acids of low toxicity is reported. The selectivity of this reaction ca...

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Detalles Bibliográficos
Autores principales: Wang, Jiandong, Ogawa, Yuta, Shibata, Norio
Formato: Online Artículo Texto
Lenguaje:English
Publicado: Nature Publishing Group UK 2019
Materias:
Article
Acceso en línea:https://www.ncbi.nlm.nih.gov/pmc/articles/PMC6911048/
https://www.ncbi.nlm.nih.gov/pubmed/31836738
http://dx.doi.org/10.1038/s41598-019-55206-7

Internet

https://www.ncbi.nlm.nih.gov/pmc/articles/PMC6911048/
https://www.ncbi.nlm.nih.gov/pubmed/31836738
http://dx.doi.org/10.1038/s41598-019-55206-7

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